GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：Ethane, 1,2-dichlorotetrafluoro-
CAS：76-14-2
Result：
| ID: | 775 |
| Classifier: | Inter-ministerial Committee on GHS |
| Year Classified: | FY2006 |
| Reference Manual: | GHS Classification Manual （10 Feb, 2006） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - | - | Gas (GHS definition) |
| 2 | Flammable gases （including chemically unstable gases） | Not classified | - | - | - | - | Non-combustible UNRTDG Class: 2.2 |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | UNRTDG Class: 2.2 |
| 5 | Gases under pressure | Liquefied gas |
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Warning | H280: Contains gas under pressure; may explode if heated | P410+P403: Protect from sunlight. Store in a well-ventilated place. | Transported as refrigerated liquefied gases (UNRTDG) |
| 6 | Flammable liquids | Not applicable | - | - | - | - | Gas (GHS definition) |
| 7 | Flammable solids | Not applicable | - | - | - | - | Gas (GHS definition) |
| 8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | Gas (GHS definition) |
| 9 | Pyrophoric liquids | Not applicable | - | - | - | - | Gas (GHS definition) |
| 10 | Pyrophoric solids | Not applicable | - | - | - | - | Gas (GHS definition) |
| 11 | Self-heating substances and mixtures | Not applicable | - | - | - | - | Gas (GHS definition) |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - | - | Gas (GHS definition) |
| 13 | Oxidizing liquids | Not applicable | - | - | - | - | Gas (GHS definition) |
| 14 | Oxidizing solids | Not applicable | - | - | - | - | Gas (GHS definition) |
| 15 | Organic peroxides | Not applicable | - | - | - | - | Gas (GHS definition) |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to gas substances are not available |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Not applicable | - | - | - | - | Gas (GHS definition) |
| 1 | Acute toxicity （Dermal） | Not applicable | - | - | - | - | Gas (GHS definition) |
| 1 | Acute toxicity （Inhalation: Gases） | Not classified | - | - | - | - | It was considered as the outside of Category according to the value of 700000, 720000, and 750000ppm in the rat LC50 (PATTY (5th, 2002)). |
| 1 | Acute toxicity （Inhalation: Vapours） | Not applicable | - | - | - | - | Gas (GHS definition) |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Not applicable | - | - | - | - | Gas (GHS definition) |
| 2 | Skin corrosion/irritation | Not classified | - | - | - | - | Irritation is not observed on rabbit skin as a result of spray medication with concentration of 40%. (EHC113 (1990), ACGIH (2001)). And also irritation was not observed as a test result of direct spraying on the back of the guinea pigs (EHC113 (1990)), from what stated above, it was classified as out of Category. |
| 3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | - | It was presupposed that it cannot be classified. Because there is only one case in which although inflammation is appeared in the eye of the rabbit by the spray data, there is no effect in the ocular (ACGIH (2001). |
| 4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
| 4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | It gave negative by in vitro salmonella tests (ACGIH (2001), PATTY (5th, 2001), EHC113 (1990)), however, there were no results for in vivo tests. Therefore we could not classify it. |
| 6 | Carcinogenicity | Not classified | - | - | - | - | There is a report that carcinogenic properties is not acknowledged by animal experiments (PATTY (5th, 2001), ACGIH (2001)), and it has become A4 by ACGIH which is a rating agencies. |
| 7 | Reproductive toxicity | Classification not possible | - | - | - | - | No data available |
| 8 | Specific target organ toxicity - Single exposure | Not classified | - | - | - | - | In the inhalation medication to a rat, the case had appeared in higher dosage; 300000ppm to 400000ppm, 300ppt, and 600ppt. So it carried out the outside of Category. |
| 9 | Specific target organ toxicity - Repeated exposure | Not classified | - | - | - | - | Since symptom had appeared in rat inhalation administration in a high amount dose of 1422 g/m3 (200000 ppm), it considered as the outside of Category. |
| 10 | Aspiration hazard | Not applicable | - | - | - | - | Gas (GHS definition) |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | Insufficient data available. |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
NOTE:
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* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
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Reference Manual |
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Definitions / Abbreviations |
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Model SDS by MHLW |
MHLW Website （in Japanese Only） |