GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：Turpentine oil
CAS：8006-64-2
Result：
| ID: | 849 |
| Classifier: | Inter-ministerial Committee on GHS |
| Year Classified: | FY2006 |
| Reference Manual: | GHS Classification Manual （10 Feb, 2006） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not classified | - | - | - | - | UNRTDG Class: 3 |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 5 | Gases under pressure | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 6 | Flammable liquids | Category 3 |
|
Warning | H226: Flammable liquid and vapour |
P303+P361+P353: IF ON SKIN （or hair）: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378: In case of fire: Use ... for extinction. P403+P235: Store in a well-ventilated place. Keep cool. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/.../equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents/container to ... |
Flash point: >=23degC and <=60degC, UNRTDG Class: 3, PGIII |
| 7 | Flammable solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 8 | Self-reactive substances and mixtures | Not classified | - | - | - | - | Classified in UNRTDG Class: 3 |
| 9 | Pyrophoric liquids | Not classified | - | - | - | - | Flash point: 220 - 255degC (ICSC (J), 2002) |
| 10 | Pyrophoric solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 11 | Self-heating substances and mixtures | Classification not possible | - | - | - | - | Test methods applicable to liquid substances are not available |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | UNRTDG Class: 3 |
| 13 | Oxidizing liquids | Not classified | - | - | - | - | UNRTDG Class: 3 |
| 14 | Oxidizing solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 15 | Organic peroxides | Not classified | - | - | - | - | UNRTDG Class: 3 |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | No data available |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Category 2 |
|
Danger | H300: Fatal if swallowed |
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment （see ... on this label）. P330: Rinse mouth. P405: Store locked up. P501: Dispose of contents/container to ... |
According to rat LD50 value: 5760mg/kg (DFGOT (Vol.17, 2002)), it is set as the outside of Category. But the lethal dose calculated based on deth cases in humans (ACGIH (7th, 2001)) was equivalent to about 210 to 1260 mg/kg, and covers from Category 2 to 3, we took the severer one and set it to Category 2. |
| 1 | Acute toxicity （Dermal） | Not classified | - | - | - | - | Since in dermal administration to rabbits, even 5010mg/kg did not have a case of death, it was set as the outside of Category. |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 1 | Acute toxicity （Inhalation: Vapours） | Category 3 |
|
Danger | H331: Toxic if inhaled |
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P311: Call a POISON CENTER or doctor/physician. P321: Specific treatment （see ... on this label）. P405: Store locked up. P501: Dispose of contents/container to ... |
Based on rat LC50 value (4 hour exposure): 13700mg/m3 (equivalent: 2450ppm), it was judged as steam which does not include mist. And was classified as Category 3. |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - | - | No data available |
| 2 | Skin corrosion/irritation | Category 2 |
|
Warning | H315: Causes skin irritation |
P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P321: Specific treatment （see ... on this label）. P362: Take off contaminated clothing and wash before reuse. |
It was set as Category 2 from description that there was irritation to the human skin (ACGIH (7th, 2001), PATTY(4th, 1994) Vol.II, 1267-1292, DFGOT (Vol.17, 2002)), and that strong irritation was in the rabbit skin (RTECS (Access on Aug 2005)). |
| 3 | Serious eye damage/eye irritation | Category 1 |
|
Danger | H318: Causes serious eye damage |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P280: Wear protective gloves/protective clothing/eye protection/face protection. P310: Immediately call a POISON CENTER or doctor/physician. |
There is the description that there are severe irritations and caustic to the eye of the humans (PATTY (4th, 1994)), as judging that there was critical eye damage. And it was set as Category 1. |
| 4 | Respiratory sensitization | Classification not possible | - | - | - | - | Although the case reports which suggests respiratory sensitizing property and allergic rhinitis for the human is mentioned in DFGOT/(Vol.14, 2000), we could not classify it because of insufficiency of data, for there were no other examples of such reports. |
| 4 | Skin sensitization | Category 1 |
|
Warning | H317: May cause an allergic skin reaction |
P302+P352: IF ON SKIN: Wash with plenty of soap and water. P333+P313: If skin irritation or rash occurs: Get medical advice/attention. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P272: Contaminated work clothing should not be allowed out of the workplace. P280: Wear protective gloves/protective clothing/eye protection/face protection. P321: Specific treatment （see ... on this label）. P363: Wash contaminated clothing before reuse. P501: Dispose of contents/container to ... |
We classified it as Category 1 based on the descriptions that it has skin sensitizing property in the epidemiological survey for occupation exposure in the human in Japan Society For Occupational Health Advice (1993), ACGIH (7th, 2001), DFGOT (Vol.14, 2000), PATTY(4th, 1994), and likewise on the description that it gave positive in the tests with the Maximization method in the guinea pig of DFGOT (vol.14 2000). |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | No data available |
| 6 | Carcinogenicity | Not classified | - | - | - | - | Since it was classified into A4 in ACGIH (ACGIH 7th, 2001), it was considered as the outside of Category. |
| 7 | Reproductive toxicity | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
| 8 | Specific target organ toxicity - Single exposure | Category 1 (kidney), Category 3 (respiratory tract irritation) |
|
Danger Warning |
H370: Causes damage to organs (kidney) H335: May cause respiratory irritation (respiratory tract irritation) |
P307+P311: IF exposed: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment （see ... on this label）. P405: Store locked up. P501: Dispose of contents/container to ... P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P312: Call a POISON CENTER or doctor/physician if you feel unwell. |
From description that there are incidence of renal impairment and airway mucosa irritation by acute exposure in the humans of industrial hygene academic society advice (1993), ACGIH (7th, 2001), and PATTY (4th, 1994). So it was set as Category 1 (kidney) and Category 3 (respiratory irritant). |
| 9 | Specific target organ toxicity - Repeated exposure | Category 1 (kidney, respiratory system) |
|
Danger | H372: Cause damage to organs through prolonged or repeated exposure (kidney, respiratory system) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
It was classified into Category 1 (kidney, respiratory organs) dueing to descriptions that respiratory disorders, such as chronic bronchitis, and a renal damage were observed in humans with the long-term occupational exposure (Japan Society for Occupational Health Recommendation of Occupational Exposure Limits (1993), DFGOT vol.17 (2002), and PATTY (4th, 1994)). |
| 10 | Aspiration hazard | Category 1 |
|
Danger | H304: May be fatal if swallowed and enters airways |
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P405: Store locked up. P501: Dispose of contents/container to ... |
Based on the descriptions that when it is aspirated into the airway by the aspiration (ACGIH (7th, 2001), PATTY (4th, 1994), DFGOT (Vol.17, 2002), ICSC (J) (2002)), it may cause the chemical pneumonia, we classified it as Category 1. |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | No data available |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | No data available. |
NOTE:
|
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
|
Reference Manual |
|
|
Definitions / Abbreviations |
|
|
Model SDS by MHLW |
MHLW Website （in Japanese Only） |