GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：zinc permanganate
CAS：23414-72-4
Result：
| ID: | 1106 |
| Classifier: | Inter-ministerial Committee on GHS |
| Year Classified: | FY2006 |
| Reference Manual: | GHS Classification Manual （10 Feb, 2006） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. The substance is high reactive and a contact of the substance with organic compounds could cause an explosion. (Bretherick, 6th, 1999) |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | Solid (GHS definition) |
| 5 | Gases under pressure | Not applicable | - | - | - | - | Solid (GHS definition) |
| 6 | Flammable liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 7 | Flammable solids | Not classified | - | - | - | - | Nonflammable (HSDB, 2002). (However, this product is a strong oxidizers and when it contacts with a reducing agent, it may burn. (Sax, 11th, 2004)) |
| 8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | Classified in oxidizing solids |
| 9 | Pyrophoric liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 10 | Pyrophoric solids | Not classified | - | - | - | - | Nonflammable (HSDB, 2002). (However, this substance is highly reactive, and when it contacts an organic matter, it may ignite spontaneously. (HSDB, 2002)) |
| 11 | Self-heating substances and mixtures | Not classified | - | - | - | - | Not combustible. (HSDB (2002)) |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | Stable to water (soluble in water) |
| 13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 14 | Oxidizing solids | Category 2 |
|
Danger | H272: May intensity fire; oxidizer |
P370+P378: In case of fire: Use ... for extinction. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P220: Keep/Store away from clothing/.../combustible materials. P221: Take any precaution to avoid mixing with combustibles/... P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents/container to ... |
UNRTDG No. 1515, Class: 5.1; PG II. |
| 15 | Organic peroxides | Not applicable | - | - | - | - | Inorganic compound |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to solid substances are not available. |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Dermal） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 1 | Acute toxicity （Inhalation: Vapours） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - | - | No data available |
| 2 | Skin corrosion/irritation | Classification not possible | - | - | - | - | There is description that skin irritation is present in humans (HSFS (2000)). But there is no data which is supported, and since data is insufficient, it cannot be classified. |
| 3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | - | Although there is the description that it irritates to human eye in HSFS (2000), there is no data which is supported, and data is insufficient. Therefore, it cannot be classified. |
| 4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
| 4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | No data available |
| 6 | Carcinogenicity | Classification not possible | - | - | - | - | Although it is categorized as zinc compounds into I in IRIS (2005) (corresponding to outer Category) , due to insufficient data, it cannot be classified. |
| 7 | Reproductive toxicity | Classification not possible | - | - | - | - | Although it is assumed that there is reproductive toxicity as a manganese compounds (ACGIH-TLV (2004)), MAK/BAT (2004) has statement that it has no reproductive toxicity. There is no data of this product, so it cannot be classified due to insufficient data. |
| 8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - | - | Although there are reports of airway irritant properties in HSFS (2000), there are no supporting data, so the substance cannot be classified due to insufficient data. |
| 9 | Specific target organ toxicity - Repeated exposure | Category 1 (central nervous system, lung) |
|
Danger | H372: Cause damage to organs through prolonged or repeated exposure (central nervous system, lung) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
Although there is no data about this product, in ACGIH-TLV (2004) of Priority 1 document, it is supposed that it has effects on a central nervous systems (manganism) and lungs by repeated exposure of manganese compounds. It was classified into Category 1 (a central nervous systems, lung). |
| 10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | No data available |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | No data available. |
NOTE:
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* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
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Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website （in Japanese Only） |
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Model SDS by MHLW |
MHLW Website （in Japanese Only） |