GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：Sulfuric acid, cadmium salt(1:1), hydrate (8/3)
CAS：7790-84-3
Result：
| ID: | 1155 |
| Classifier: | Inter-ministerial Committee on GHS |
| Year Classified: | FY2006 |
| Reference Manual: | GHS Classification Manual （10 Feb, 2006） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | Solid (GHS definition) |
| 5 | Gases under pressure | Not applicable | - | - | - | - | Solid (GHS definition) |
| 6 | Flammable liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 7 | Flammable solids | Not classified | - | - | - | - | Nonflammable. (GESTIS-database on hazardous substancess of cadmium sulfate (anhydride) (Accessed on Apr.2006) has a statement that it is "nonflammable".)) |
| 8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups associated with explosive or self-reactive properties present in the molecule. |
| 9 | Pyrophoric liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 10 | Pyrophoric solids | Not classified | - | - | - | - | Nonflammable. (GESTIS-database on hazardous substancess (Accessed on Apr.2006) of cadmium sulfate (anhydride) has a statement that it is "nonflammable".) |
| 11 | Self-heating substances and mixtures | Not classified | - | - | - | - | Nonflammable. (GESTIS-database on hazardous substancess (Accessed on Apr.2006) of cadmium sulfate (anhydride) has a "nonflammable" statement.) |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | Stable to water (readily soluble) |
| 13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
| 14 | Oxidizing solids | Classification not possible | - | - | - | - | No data available |
| 15 | Organic peroxides | Not applicable | - | - | - | - | Inorganic compound |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to solid substances are not available. |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Classification not possible | - | - | - | - | No data. (According to the risk phrases in EU-Annex I (Access on Jun. 2005) for cadmium sulfate (anhydride), its oral toxicity is high.) * Because the data available for this substance is limited, also refer to the classification results of cadmium sulfate (anhydride) (ID No.0254, CAS No.10108-64-2) for each item related to its health hazards. |
| 1 | Acute toxicity （Dermal） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - | - | Solid (GHS definition) |
| 1 | Acute toxicity （Inhalation: Vapours） | Classification not possible | - | - | - | - | No data available |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - | - | Data without. (In the risk phrases of EU-Annex I (Access on Jun.2005) of cadmium sulfate (anhydride), it is supposed that inhalation toxicity is very high.) |
| 2 | Skin corrosion/irritation | Classification not possible | - | - | - | - | No data available |
| 3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | - | No data available |
| 4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
| 4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
| 5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | No data. (germ cell mutagenicities of cadmium sulfate (anhydride) is suspected from EU-Annex I (Access on Jun.2005) and the class of MAK/BAT (2004) (respectively respectively Muta.Cat.2 and 3A) |
| 6 | Carcinogenicity | Category 1A-1B |
|
Danger | H350: May cause cancer |
P308+P313: IF exposed or concerned: Get medical advice/attention. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. P405: Store locked up. P501: Dispose of contents/container to ... |
It is categorized into Category 1A as cadmium compounds (Group 1, Known to be human carcinogens, 1respectively) in IARC53 (1993), NTP RoC (11th, 2005) and industrial hygene academic society advice (2004), the classification (Carc.Cat.2) as cadmium compounds in IRIS(1992) and ACGIH-TLV(2004)(B1, A2, respectively) and as cadmium sulfate (anhydride) in EU-Annex I (Access on Jun.2005) are categorized into Category 1B. Since the newness etc. of sources of the both Category were almost equivalent, it was classified into Category 1A-1B. [Indication] 1A is recommended based on the safety, when the Category needs to subdivide. |
| 7 | Reproductive toxicity | Category 1B |
|
Danger | H360: May damage fertility or the unborn child |
P308+P313: IF exposed or concerned: Get medical advice/attention. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. P405: Store locked up. P501: Dispose of contents/container to ... |
In California Proposition 65 (California EPA/OEHHA, 2005), it is registered as cadmium having reproductive toxicity in sire. It was set as Category 1B. |
| 8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - | - | No data available. |
| 9 | Specific target organ toxicity - Repeated exposure | Category 1 (kidney) |
|
Danger | H372: Cause damage to organs through prolonged or repeated exposure (kidney) |
P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P314: Get medical advice/attention if you feel unwell. P501: Dispose of contents/container to ... |
Although there is no data of this product, there is a description of an effect on kidneys caused by repeated exposure of cadmium compounds (ACGIH-TLV (2004) in Priority 1 document). Therefore, it was classified into Category 1 (kidney). |
| 10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | No data available |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | No data available. |
NOTE:
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* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
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Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website （in Japanese Only） |
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Model SDS by MHLW |
MHLW Website （in Japanese Only） |