Chemical Name:Tributyl(methacryloyloxy)stannane
CAS:2155-70-6
ID: | 1415 |
Classifier: | Inter-ministerial Committee on GHS |
Year Classified: | FY2006 |
Reference Manual: | GHS Classification Manual (10 Feb, 2006) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Explosives | Not applicable | - | - | - | - | Containing no chemical groups with explosive properties |
2 | Flammable gases (including chemically unstable gases) | Not applicable | - | - | - | - | Classified as "liquid" or "solid" according to GHS definition |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
4 | Oxidizing gases | Not applicable | - | - | - | - | Classified as "liquid" or "solid" according to GHS definition |
5 | Gases under pressure | Not applicable | - | - | - | - | Classified as "liquid" or "solid" according to GHS definition |
6 | Flammable liquids | Classification not possible (as a liquid) | - | - | - | - | No data available |
7 | Flammable solids | Classification not possible (as a solid) | - | - | - | - | No data available |
8 | Self-reactive substances and mixtures | Classification not possible | - | - | - | - | Classification not possible due to lack of data, though containing unsaturated bonds (olefin) |
9 | Pyrophoric liquids | Classification not possible (as a liquid) | - | - | - | - | No data available |
10 | Pyrophoric solids | Classification not possible (as a solid) | - | - | - | - | No data available |
11 | Self-heating substances and mixtures | Classification not possible | - | - | - | - | Test methods applicable to liquid substances are not available (the melting point is 16degC (EHC 116 (1990)) and 21.5degC (PRTR Chemicals DB (2001)) (test temperature: 140degC)). |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Classification not possible | - | - | - | - | Classification not possible due to lack of data, though containing Sn (a metalloid) |
13 | Oxidizing liquids | Classification not possible (as a liquid) | - | - | - | - | Classification not possible due to lack of data, though being organic compounds containing oxygen bound to elements other than carbon and hydrogen |
14 | Oxidizing solids | Classification not possible (as a solid) | - | - | - | - | Classification not possible due to lack of data, though being organic compounds containing oxygen bound to elements other than carbon and hydrogen |
15 | Organic peroxides | Not applicable | - | - | - | - | Organic compounds containing no "-O-O-" structure |
16 | Corrosive to metals | Classification not possible | - | - | - | - | No data available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Category 3 | Danger | H301: Toxic if swallowed |
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P321: Specific treatment (see ... on this label). P330: Rinse mouth. P405: Store locked up. P501: Dispose of contents/container to ... |
Based on the rat LD50 (oral route) value of 160mg/kg (RTECS (2006)). | |
1 | Acute toxicity (Dermal) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Inhalation: Gases) | Not applicable | - | - | - | - | Due to the fact that the substance is a liquid or solid according to the GHS definition and inhalation of its gas is not expected. |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible | - | - | - | - | No data available |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible | - | - | - | - | No data available |
2 | Skin corrosion/irritation | Classification not possible | - | - | - | - | No data available. As for the health hazards, refer to "ID428, Tributyl Tin Chloride, CAS: 1461-22-9." |
3 | Serious eye damage/eye irritation | Classification not possible | - | - | - | - | No data available. As for the health hazards, refer to "ID428, Tributyl Tin Chloride, CAS: 1461-22-9." |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available |
4 | Skin sensitization | Classification not possible | - | - | - | - | No data available |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | No data available |
6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available |
7 | Reproductive toxicity | Classification not possible | - | - | - | - | No data available |
8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - | - | No data available. Refer to "Tributyl Tin Oxide (ID: 1275, CAS: 56-35-9)." |
9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | - | No data available. Refer to "Tributyl Tin Oxide (ID: 1275, CAS: 56-35-9)." |
10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Category 1 | Warning | H400: Very toxic to aquatic life |
P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to ... |
It was classified into Category 1 from 96 hours LC50=3.2ppb of the crustacea (Mysid Shrimp)) (AQUIRE, 2003). | |
11 | Hazardous to the aquatic environment (Long-term) | Category 1 | Warning | H410: Very toxic to aquatic life with long lasting effects |
P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to ... |
Since acute toxicity was Category 1 and there was no rapidly degrading (it was hydrolyzed, and triphenyltin hydroxide was generated, and was residue(existing chemical safety inspections data)), and since there was bio-accumulation (BCF=9210(triphenyltin hydroxide) (existing chemical safety inspections data)), it was classified into Category 1. |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website (in Japanese Only) |
Model SDS by MHLW |
MHLW Website (in Japanese Only) |