Chemical Name:Sodium alpha-dodecan-1-yl-omega-(sulfonatooxy)poly(oxyethylene)
CAS:9004-82-4
ID: | 1-409 |
Classifier: | Ministry of Economy, Trade and Industry (METI), Ministry of the Environment (MOE) |
Year Classified: | FY2008 |
Reference Manual: | GHS Classification Guidance by the Japanese Government (Sep, 2008) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecules. |
2 | Flammable gases (including chemically unstable gases) | Not applicable | - | - | - | - | Solid |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products |
4 | Oxidizing gases | Not applicable | - | - | - | - | Solid |
5 | Gases under pressure | Not applicable | - | - | - | - | Solid |
6 | Flammable liquids | Not applicable | - | - | - | - | Solid |
7 | Flammable solids | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups associated with explosive or self-reactive properties present in the molecule. |
9 | Pyrophoric liquids | Not applicable | - | - | - | - | Solid |
10 | Pyrophoric solids | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
11 | Self-heating substances and mixtures | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - | - | Metals or metalloids (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At) are not included. |
13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid |
14 | Oxidizing solids | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
15 | Organic peroxides | Not applicable | - | - | - | - | The organic compound not including peroxy group in molecule. |
16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to solid substances are not available. |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
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1 | Acute toxicity (Oral) | Category 4 | Warning | H302: Harmful if swallowed |
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P330: Rinse mouth. P501: Dispose of contents/container to ... |
In the information on List3, since LD50 value of the oral administration test employing a rat is 1,600 mg/kg (RTECS (1999)), it was classified into Category 4. | |
1 | Acute toxicity (Dermal) | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
1 | Acute toxicity (Inhalation: Gases) | Not applicable | - | - | - | - | Since it was a solid by the definition of GHS and inhalation in gas was not assumed, it was classified into "Not applicable". |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
2 | Skin corrosion/irritation | Category 2 | Warning | H315: Causes skin irritation |
P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P321: Specific treatment (see ... on this label). P362: Take off contaminated clothing and wash before reuse. |
Since there are descriptions, "Skin irritation and dermal dryness due to occupational contacts for a long period of time have been reported," HSDB (2002) as its toxicity effects on humans and "One with a short Ethylene oxide chain has stronger irritation against guinea pig and rabbits," regarding animals, it was classified in Category 2. In addition, there is a description, "severe" (RTECS (1997)) and "moderate" (RTECS (1999)), in the 24 hour Draize test using rabbits for the information source of List 3. | |
3 | Serious eye damage/eye irritation | Category 2 | Warning | H319: Causes serious eye irritation |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. |
In the information source of List3, there is a description of "moderate" (RTECS (1997)) and "severe" (RTECS (1999)) in the 24-hour Draize test employing the rabbit. Moreover, since the this substance was a skin irritation substance, it was classified into Category 2 according to Fig. 3.3.1 of the of the U.N. GHS second edition. | |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | Although there is a description of "occupational asthmas in humans" (HSDB (2002)), classification is not possible because of unknown details and no other data. |
4 | Skin sensitization | Classification not possible | - | - | - | - | Classification is not possible because of no data. |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
6 | Carcinogenicity | Classification not possible | - | - | - | - | Since no evaluation by major international evaluation agencies is made and there is no data, classification is not possible. |
7 | Reproductive toxicity | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
8 | Specific target organ toxicity - Single exposure | Category 2 (digestive system) | Warning | H371: May cause damage to organs (digestive system) |
P309+P311: IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P405: Store locked up. P501: Dispose of contents/container to ... |
Since there was a description of "Vomiting, nausea, and diarrhea were seen when it was ingested" as acute toxicity symptoms of human (HSDB (2002), it was classified into Category 2 (digestive system). | |
9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | - | Classification not possible due to lack of data |
10 | Aspiration hazard | Category 1 | Danger | H304: May be fatal if swallowed and enters airways |
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P405: Store locked up. P501: Dispose of contents/container to ... |
Judging from the description about the effects to human that "upper airway edema and dyspnea respiratory distress may be caused by inhalation"(HSDB (2002)), it was classified into Category 1. |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Category 2 | - | - | H401: Toxic to aquatic life |
P273: Avoid release to the environment. P501: Dispose of contents/container to ... |
It was classified into Category 2 from 48 hours EC50=3.12mg/L of the crustacea (Ceriodaphnia) (AQUIRE (2008)). |
11 | Hazardous to the aquatic environment (Long-term) | Category 2 | - | H411: Toxic to aquatic life with long lasting effects |
P273: Avoid release to the environment. P391: Collect spillage. P501: Dispose of contents/container to ... |
Since acute toxicity was Category 2 and there were no data about rapid degradability, it was classified into Category 2. |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website (in Japanese Only) |
Model SDS by MHLW |
MHLW Website (in Japanese Only) |