NITE - Chemical Management Field

GHS Classification Result

Chemical Name：7-methylocta-1,6-diene
CAS：42152-47-6

Result：


ID:	20A2277
Classifier:	Ministry of Health, Labour and Welfare （MHLW）, Ministry of the Environment （MOE）
Year Classified:	FY2008
Reference Manual:	GHS Classification Guidance by the Japanese Government （Sep, 2008）

PHYSICAL HAZARDS

Hazard class		Classification	Symbol	Signal word	Hazard statement	Precautionary statement	Rationale for the classification
1	Explosives	Not applicable	-	-	-	-	There are no chemical groups associated with explosive properties present in the molecules.
2	Flammable gases （including chemically unstable gases）	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
3	Aerosols	Not applicable	-	-	-	-	Not aerosol products.
4	Oxidizing gases	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
5	Gases under pressure	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
6	Flammable liquids	Category 3		Warning	H226: Flammable liquid and vapour	P303+P361+P353: IF ON SKIN （or hair）: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378: In case of fire: Use ... for extinction. P403+P235: Store in a well-ventilated place. Keep cool. P210: Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/.../equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents/container to ...	Its flash point is between 23 and 60degC.
7	Flammable solid	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
8	Self-reactive substances and mixtures	Classification not possible	-	-	-	-	The molecule contains chemical groups associated with self-reactive properties. Classification is not possible due to lack of data.
9	Pyrophoric liquids	Classification not possible	-	-	-	-	No data available.
10	Pyrophoric solids	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
11	Self-heating substances and mixtures	Classification not possible	-	-	-	-	Test methods applicable to liquid substances are not available.
12	Substances and mixtures which, in contact with water, emit flammable gases	Not applicable	-	-	-	-	The chemical structure of the substance does not contain metals or metalloids (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
13	Oxidizing liquids	Not applicable	-	-	-	-	Organic compounds containing no oxygen, fluorine or chlorine
14	Oxidizing solids	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
15	Organic peroxides	Not applicable	-	-	-	-	Organic compounds containing no bivalent -O-O- structure in the molecule
16	Corrosive to metals	Classification not possible	-	-	-	-	No data available.

HEALTH HAZARDS

Hazard class		Classification	Symbol	Signal word	Hazard statement	Precautionary statement	Rationale for the classification
1	Acute toxicity （Oral）	Classification not possible	-	-	-	-	No data available.
1	Acute toxicity （Dermal）	Classification not possible	-	-	-	-	No data available.
1	Acute toxicity （Inhalation: Gases）	Not applicable	-	-	-	-	Liquid (room temperature) (GESTIS (accessed in January 2009))
1	Acute toxicity （Inhalation: Vapours）	Classification not possible	-	-	-	-	No data available.
1	Acute toxicity （Inhalation: Dusts and mists）	Classification not possible	-	-	-	-	No data available.
2	Skin corrosion/irritation	Classification not possible	-	-	-	-	No data available.
3	Serious eye damage/eye irritation	Classification not possible	-	-	-	-	No data available.
4	Respiratory sensitization	Classification not possible	-	-	-	-	No data available.
4	Skin sensitization	Classification not possible	-	-	-	-	No data available.
5	Germ cell mutagenicity	Classification not possible	-	-	-	-	No data available.
6	Carcinogenicity	Classification not possible	-	-	-	-	No data available.
7	Reproductive toxicity	Classification not possible	-	-	-	-	No data available.
8	Specific target organ toxicity - Single exposure	Classification not possible	-	-	-	-	No data available.
9	Specific target organ toxicity - Repeated exposure	Classification not possible	-	-	-	-	No data available.
10	Aspiration hazard	Classification not possible	-	-	-	-	No data available.

ENVIRONMENTAL HAZARDS

Hazard class		Classification	Symbol	Signal word	Hazard statement	Precautionary statement	Rationale for the classification
11	Hazardous to the aquatic environment （Acute）	Not classified	-	-	-	-	Its 72-hour ErC50 was > 0.022 mg/L for algae (Raphidocelis subcapitata), 48-hour EC50 was > 0.51 mg/L for crustacea (Daphnia magna), and 96-hour LC50 was > 0.52 mg/L for fish (Oryzias latipes) (all, limit test (for algae calculated from measurements at the beginning and end of exposure; for crustaceans and fish, measurements at the beginning of exposure), Results of Aquatic Toxicity Tests of Chemicals conducted by Ministry of the Environment in Japan (Ministry of the Environment, 2000)). As above, since reliable studies on algae, crustacea, and fish were obtained and no effects were observed at any concentration tested, the acute toxicity of this substance was judged to be low and it was classified as "Not classified."
11	Hazardous to the aquatic environment （Long-term）	Category 4	-	-	H413: May cause long lasting harmful effects to aquatic life	P273: Avoid release to the environment. P501: Dispose of contents/container to ...	Its acute aquatic toxicity using concentrations up to its water solubility has not been documented. Although its classification for acute toxicity is "Not classified," it is not water soluble (estimated water solubility: 4.313 mg/L (WSKOWWIN). In addition, its rapid degradability has not been reported, its log Kow is > 4 (estimated value: 4.47 (KOWWIN), and its 21-day NOEC = 0.24 mg/L for crustaceans (< 1 mg/L, Test for the Ecological Effect of Chemical Substances (Ministry of the Environment), 2002). All these pieces of information considered, the substance was classified into Category 4.

NOTE:

* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.

Reference：

Reference Manual
Definitions / Abbreviations
Model Label by MHLW	MHLW Website （in Japanese Only）
Model SDS by MHLW	MHLW Website （in Japanese Only）