GHS Classification Result

Chemical Name:Hydrogen hexachloroplatinate (IV)
CAS:16941-12-1

Result:
ID: 21A3537
Classifier: Ministry of Health, Labour and Welfare (MHLW), Ministry of the Environment (MOE)
Year Classified: FY2009
Reference Manual: GHS Classification Guidance by the Japanese Government (March, 2009)

PHYSICAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Explosives Not applicable - - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases (including chemically unstable gases) Not applicable - - - - Solid (GHS definition)
3 Aerosols Not applicable - - - - Not aerosol products.
4 Oxidizing gases Not applicable - - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - - Solid (GHS definition)
7 Flammable solids Not classified - - - - Classified into Not classified since the substance is Non-combustible solid (GESTIS (access on Aug. 2009)).
8 Self-reactive substances and mixtures Not applicable - - - - There are no chemical groups present in the molecule associated with explosive or self-reactive properties.
9 Pyrophoric liquids Not applicable - - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - - Classified into Not classified since the substance is Non-combustible solid (GESTIS (access on Aug. 2009)).
11 Self-heating substances and mixtures Not classified - - - - Classified into Not classified since the substance is Non-combustible solid (GESTIS (access on Aug. 2009)).
12 Substances and mixtures which, in contact with water, emit flammable gases Not classified - - - - Classified into Not classified since the substance is "Easily soluble in water" (Merck (14th, 2006)) though it contains metal (Pt).
13 Oxidizing liquids Not applicable - - - - Solid (GHS definition)
14 Oxidizing solids Classification not possible - - - - No data available.
15 Organic peroxides Not applicable - - - - Inorganic compound
16 Corrosive to metals Classification not possible - - - - Test methods applicable to solid substances are not available.

HEALTH HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Acute toxicity (Oral) Classification not possible - - - - No data available. As relevant information, the substance is classified into R25 in EU classification (EU-Annex I (2009)).
1 Acute toxicity (Dermal) Classification not possible - - - - No data available.
1 Acute toxicity (Inhalation: Gases) Not applicable - - - - Solid (GHS definition)
1 Acute toxicity (Inhalation: Vapours) Classification not possible - - - - No data available.
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible - - - - No data available.
2 Skin corrosion/irritation Classification not possible - - - - No data available. As relevant information, in EU classification, the substance is classified into R34 (EU-Annex I (2009)).
3 Serious eye damage/eye irritation Classification not possible - - - - No data available.
4 Respiratory sensitization Category 1 Danger H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled P304+P341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342+P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P285: In case of inadequate ventilation wear respiratory protection.
P501: Dispose of contents/container to ...
This substance is one of the compounds responsible for platinum salt hypersensitivity. The signs and symptoms of hypersensitivity include urticarial, contact dermatitis of the skin, and respiratory disorders ranging from sneezing, shortness of breath, and cyanosis to severe asthma (EHC (J) No.125 (2000)). In Japan Society For Occupational Health (JSOH), the following statement is found: "occupational exposure to water-soluble platinum salts causes allergic reaction, and asthmatic symptoms and skin sensitization are observed". Water-soluble platinum salts were classified as sensitizer (Category 1 for the respiratory tract and skin) (Recommendations for allowable concentrations (2008 and 2000)). The substance is water-soluble (Merck (14th, 2006)). Based on these information, the substance was classified into Category 1. As relevant information, the substance is classified into R42/43 in EU classification (EU-Annex I (access on July 2009)) and Asthma mark is assigned in ACGIH (ACGIH-TLV (2009)).
4 Skin sensitization Category 1 Warning H317: May cause an allergic skin reaction P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P333+P313: If skin irritation or rash occurs: Get medical advice/attention.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P272: Contaminated work clothing should not be allowed out of the workplace.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P321: Specific treatment (see ... on this label).
P363: Wash contaminated clothing before reuse.
P501: Dispose of contents/container to ...
The substance is one of the compounds responsible for platinum salt hypersensitivity. The signs and symptoms of hypersensitivity include urticarial, contact dermatitis of the skin, and respiratory disorders ranging from sneezing, shortness of breath, and cyanosis to severe asthma (EHC (J) No.125 (2000)). In Japan Society For Occupational Health (JSOH), the following statement is found: "occupational exposure to water-soluble platinum salts causes allergic reaction, and asthmatic symptoms and skin sensitization are observed". Water-soluble platinum salts were classified as sensitizer (Category 1 for the respiratory tract and skin) (Recommendations for allowable concentrations (vol.50 (2008) and vol.42 (2000)). The substance is water-soluble (Merck (14th, 2006)). The substance was classified into Category 1. As relevant information, the substance is classified into R42/43 in EU classification (EU-Annex I (2009)).
5 Germ cell mutagenicity Classification not possible - - - - No data available.
6 Carcinogenicity Classification not possible - - - - No data available.
7 Reproductive toxicity Classification not possible - - - - No data available.
8 Specific target organ toxicity - Single exposure Classification not possible - - - - No data available.
9 Specific target organ toxicity - Repeated exposure Classification not possible - - - - No data available.
10 Aspiration hazard Classification not possible - - - - No data available.

ENVIRONMENTAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
11 Hazardous to the aquatic environment (Acute) Classification not possible - - - - Classification not possible due to lack of data.
11 Hazardous to the aquatic environment (Long-term) Classification not possible - - - - Classification not possible due to lack of data.


NOTE:
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.

Reference:
Reference Manual

Definitions / Abbreviations

Model Label by MHLW

MHLW Website (in Japanese Only)

Model SDS by MHLW

MHLW Website (in Japanese Only)


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