Chemical Name:Potassium carbonate
CAS:584-08-7
ID: | 22A4004 |
Classifier: | Ministry of Health, Labour and Welfare (MHLW), Ministry of the Environment (MOE) |
Year Classified: | FY2010 |
Reference Manual: | GHS Classification Guidance by the Japanese Government (July, 2010) |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecule. |
2 | Flammable gases (including chemically unstable gases) | Not applicable | - | - | - | - | Solid (GHS definition) |
3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products. |
4 | Oxidizing gases | Not applicable | - | - | - | - | Solid (GHS definition) |
5 | Gases under pressure | Not applicable | - | - | - | - | Solid (GHS definition) |
6 | Flammable liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
7 | Flammable solids | Not classified | - | - | - | - | Not combustible (ICSC (J) (2005)) |
8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups present in the molecule associated with explosive or self-reactive properties. |
9 | Pyrophoric liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
10 | Pyrophoric solids | Not classified | - | - | - | - | Not combustible (ICSC (J) (2005)) |
11 | Self-heating substances and mixtures | Not classified | - | - | - | - | Not combustible (ICSC (J) (2005)) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified | - | - | - | - | Although it contains a metal (K), its water solubility is 111 g/100 mL (Lide (88th, 2008)) and it is considered stable in contact with water. The substance was classified as "Not classified". |
13 | Oxidizing liquids | Not applicable | - | - | - | - | Solid (GHS definition) |
14 | Oxidizing solids | Not classified | - | - | - | - | This substance is inorganic compound containing oxygen, but it is classified as "Not classified" based on the description of "Niet van toepassing" (Dutch: Not correspond) (IUCLID (2000)). |
15 | Organic peroxides | Not applicable | - | - | - | - | Inorganic compound |
16 | Corrosive to metals | Classification not possible | - | - | - | - | Test methods applicable to solid substances are not available. |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Category 4 | Warning | H302: Harmful if swallowed |
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P264: Wash ... thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P330: Rinse mouth. P501: Dispose of contents/container to ... |
The two LD50 values for rats were documented to be 1870 mg/kg (HSDB (2001), IUCLID (2000)), and > 2000 mg/kg (IUCLID (2000)). Based on the data, Category 4 or "Not classified" (corresponding to Category 5 or "Not classified" in the UN-GHS classification) were adopted for the substance. Therefore, from the viewpoint of selecting the category with greater hazard, the substance was classified as Category 4. | |
1 | Acute toxicity (Dermal) | Classification not possible | - | - | - | - | No data available. |
1 | Acute toxicity (Inhalation: Gases) | Not applicable | - | - | - | - | Solid (GHS definition) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible | - | - | - | - | No data available. |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible | - | - | - | - | No data available. |
2 | Skin corrosion/irritation | Category 2 | Warning | H315: Causes skin irritation |
P302+P352: IF ON SKIN: Wash with plenty of soap and water. P332+P313: If skin irritation occurs: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. P321: Specific treatment (see ... on this label). P362: Take off contaminated clothing and wash before reuse. |
The substance was classified as Category 2 based on the results of "irritating" in the Draize test using rabbits in which irritation index was 2.5 (maximum value was 8) (IUCLID (2000)). | |
3 | Serious eye damage/eye irritation | Category 2A | Warning | H319: Causes serious eye irritation |
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313: If eye irritation persists: Get medical advice/attention. P264: Wash ... thoroughly after handling. P280: Wear protective gloves/protective clothing/eye protection/face protection. |
The substance was classified as Category 2A based on the results of "irritating" in the Draize test using rabbits in which average scores of 2.17 for cornea opacity, 1.33 for iritis, 3.00 for conjunctivae redness and 4.00 for chemosis were reported, and irritation index was 63.2 (maximum value 110)(IUCLID (2000)). In another rabbit test, irrigation of the surface of the eyes with 10% solution at pH 11.6 for 30 seconds caused pain and very slight transient optical irregularity of epithelium (HSDB (2001)). | |
4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available. |
4 | Skin sensitization | Classification not possible | - | - | - | - | No data available. |
5 | Germ cell mutagenicity | Classification not possible | - | - | - | - | Because no in vivo test data available, the classification was not possible. As relevant information, as for in vitro test, there are negative results in the Ames test and the chromosomal aberration test using CHL cells (IUCLID (2000)). |
6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available. |
7 | Reproductive toxicity | Classification not possible | - | - | - | - | In the oral administration tests using pregnant rats and mice during the organogenetic period, there was no clearly discernible effect on nidation or maternal or fetal survival, and the number of abnormalities seen in either internal or skeletal tissues of the test groups did not differ from the number occurring spontaneously in the vehicle-treated controls in both species (IUCLID (2000)). However, since there was no data on the sexual functions and fertility of parental animals, the substance was classified as "Classification not possible". |
8 | Specific target organ toxicity - Single exposure | Classification not possible | - | - | - | - | No data was available. Due to alkalinity, this substance might irritate the airway via inhalation (HSDB (2001)). |
9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | - | No data available. |
10 | Aspiration hazard | Classification not possible | - | - | - | - | No data available. |
Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment (Acute) | Not classified | - | - | - | - | Classified as "Not classified" from its 48h-LC50 = 630 mg/L for crustacea (Ceriodaphnia dubia) (AQUIRE, 2011). |
11 | Hazardous to the aquatic environment (Long-term) | Not classified | - | - | - | - | Classified as "Not classified" since it is not non-water soluble (water solubility: 500000 mg/L (PHYSPROP Database, 2011)) and its acute toxicity is "Not classified". |
12 | Hazardous to the ozone layer | Classification not possible | - | - | - | - | This substance is not listed in Annexes to the Montreal Protocol. |
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website (in Japanese Only) |
Model SDS by MHLW |
MHLW Website (in Japanese Only) |