GHS Classification Result
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
Reference：
Chemical Name：Non-1-ene; 1-Nonene
CAS：124-11-8
Result：
| ID: | 22A4042 |
| Classifier: | Ministry of Health, Labour and Welfare （MHLW）, Ministry of the Environment （MOE） |
| Year Classified: | FY2010 |
| Reference Manual: | GHS Classification Guidance by the Japanese Government （July, 2010） |
PHYSICAL HAZARDS
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable | - | - | - | - | There are no chemical groups associated with explosive properties present in the molecule. |
| 2 | Flammable gases （including chemically unstable gases） | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 3 | Aerosols | Not applicable | - | - | - | - | Not aerosol products. |
| 4 | Oxidizing gases | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 5 | Gases under pressure | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 6 | Flammable liquids | Category 3 |
|
Warning | H226: Flammable liquid and vapour |
P303+P361+P353: IF ON SKIN （or hair）: Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370+P378: In case of fire: Use ... for extinction. P403+P235: Store in a well-ventilated place. Keep cool. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting/.../equipment. P242: Use only non-sparking tools. P243: Take precautionary measures against static discharge. P280: Wear protective gloves/protective clothing/eye protection/face protection. P501: Dispose of contents/container to ... |
The substance is classified into Category 3, because its flash point reported 26 degC (closed-cup) (GESTIS (Access on June. 2010)) is >= 23 degC and <= 60 degC. |
| 7 | Flammable solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 8 | Self-reactive substances and mixtures | Not applicable | - | - | - | - | There are no chemical groups present in the molecule associated with explosive or self-reactive properties. |
| 9 | Pyrophoric liquids | Not classified | - | - | - | - | Since its auto ignition point is 440 degC (458 degF; estimated) (Chemical Risk Information Platform (CHRIP) (Access on June. 2010)), it is considered that the substance does not ignite at room temperature. |
| 10 | Pyrophoric solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 11 | Self-heating substances and mixtures | Classification not possible | - | - | - | - | Test methods applicable to liquid substances are not available. |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Not applicable | - | - | - | - | The chemical structure of the substance does not contain metals or metalloids (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At). |
| 13 | Oxidizing liquids | Not applicable | - | - | - | - | Organic compounds containing no oxygen, fluorine or chlorine. |
| 14 | Oxidizing solids | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 15 | Organic peroxides | Not applicable | - | - | - | - | Organic compounds containing no bivalent -O-O- structure. |
| 16 | Corrosive to metals | Classification not possible | - | - | - | - | No data available. |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 1 | Acute toxicity （Oral） | Not classified | - | - | - | - | No data were available for this substance. The rat LD50 value of > 2332 mg/kg was documented (SIDS (Access on Jul. 2010)) for C9 rich, C8-10 alkenes (CAS No. 68526-55-6). Thus the substance was classified as "Not classified" in the JIS classification (corresponding to Category 5 in the UN-GHS classification). |
| 1 | Acute toxicity （Dermal） | Not classified | - | - | - | - | No data were available for this substance. The rabbit LD50 value of > 2332 mg/kg was documented (SIDS (Access on Jul. 2010)) for C9 rich, C8-10 alkenes (CAS No. 68526-55-6). Thus the substance was classified as "Not classified" in the JIS classification (corresponding to Category 5 in the UN-GHS classification). |
| 1 | Acute toxicity （Inhalation: Gases） | Not applicable | - | - | - | - | Liquid (GHS definition) |
| 1 | Acute toxicity （Inhalation: Vapours） | Classification not possible | - | - | - | - | No data were available for this substance. The rat LC50 (4 hour) value of >13.6 mg/L (2633 ppm) was documented (SIDS (Access on Jul. 2010)) for C9 rich, C8-10 alkenes (CAS No. 68526-55-6), this information did not provide a basis for classification. The test concentration, 2633 ppm, was less than the 90 % of the saturated vapor pressure concentration (7105 ppm), the criterion values for gas were adopted for the classification. |
| 1 | Acute toxicity （Inhalation: Dusts and mists） | Classification not possible | - | - | - | - | No data available. |
| 2 | Skin corrosion/irritation | Not classified | - | - | - | - | No data were available of the substance. But as for alkenes (CAS No. 68526-55-6, C8 - 10, C9 Rich), mild irritation which was characterized by slight erythema was reported in 24-hour skin application test in rabbits at 73.8 - 2332 mg/kg of undiluted substance (SIDS (Access on Jul. 2010)). Based on the document, the substance was classified as "Not classified" in the JIS classification (corresponding to Category 3 in the UN-GHS classification). |
| 3 | Serious eye damage/eye irritation | Not classified | - | - | - | - | No data were available of the substance. But as for alkenes (CAS No. 68526-55-6, C8 - 10, C9 Rich), mild conjunctival irritation was reported in rabbit test by instillation of 0.1 ml of undiluted substance, but symptoms disappeared within 24 hours and maximum total score of Draize was 6 (SIDS (Access on Jul. 2010)). Based on the document, the substance was classified as "Not classified". |
| 4 | Respiratory sensitization | Classification not possible | - | - | - | - | No data available. |
| 4 | Skin sensitization | Classification not possible | - | - | - | - | No data available. |
| 5 | Germ cell mutagenicity | Not classified | - | - | - | - | There are no data for this substance. As for alkenes (CAS No. 68526-55-6), C9 rich mixture with C8 - C10, negative results in the micronucleus test using bone marrow after oral administration to mice (in vivo mutagenicity test in somatic cells) were reported (SIDS (Access on Jul. 2010)). Therefore, the classification was concluded as "Not classified". As relevant information, as for in vitro study, negative results in the Ames test were reported (SIDS (Access on Jul. 2010)). |
| 6 | Carcinogenicity | Classification not possible | - | - | - | - | No data available. |
| 7 | Reproductive toxicity | Classification not possible | - | - | - | - | No data available. |
| 8 | Specific target organ toxicity - Single exposure | Category 3 （Narcotic effects） |
|
Warning | H336: May cause drowsiness or dizziness (narcotic effects) |
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P403+P233: Store in a well-ventilated place. Keep container tightly closed. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P271: Use only outdoors or in a well-ventilated area. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P405: Store locked up. P501: Dispose of contents/container to ... |
No data on this substance was available. In the acute inhalation toxicity studies of the C9 rich mixture with C8 - C10 alkenes (CAS No. 68526-55-6) in mice, rats or guinea pigs, no deaths occurred in any species at a vapor concentration of 11.1 mg/L/6hrs (converted value as that of 4-hour exposure: 13.6 mg/L), and the treatment-related clinical signs observed were as follows: labored respiration in mice, ataxia and lethargy in rats, and slight tremors in guinea pigs. No other remarkable changes were observed at necropsy (SIDS (Access on Jul. 2010)). Moreover, the rats administered orally at high dose (2332 mg/kg) showed a mild depression, while anesthetic effects were reported when exposed to this substance at high concentrations (PATTY, 5th, (2001)). As mentioned above, the substance was classified as Category 3 (narcotic effects). |
| 9 | Specific target organ toxicity - Repeated exposure | Classification not possible | - | - | - | - | No data available. |
| 10 | Aspiration hazard | Category 1 |
|
Danger | H304: May be fatal if swallowed and enters airways |
P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. P405: Store locked up. P501: Dispose of contents/container to ... |
This substance was classified as Category 1 from the fact that it is a hydrocarbon liquid and coefficient of kinematic viscosity is 1.17 mm2/s (HSDB (2002)). |
| Hazard class | Classification | Symbol | Signal word | Hazard statement | Precautionary statement | Rationale for the classification | |
|---|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment （Acute） | Classification not possible | - | - | - | - | Classification not possible due to lack of data. |
| 11 | Hazardous to the aquatic environment （Long-term） | Classification not possible | - | - | - | - | Classification not possible due to lack of data. |
| 12 | Hazardous to the ozone layer | Classification not possible | - | - | - | - | This substance is not listed in Annexes to the Montreal Protocol. |
NOTE:
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* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. |
Reference：
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Reference Manual |
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Definitions / Abbreviations |
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Model Label by MHLW |
MHLW Website （in Japanese Only） |
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Model SDS by MHLW |
MHLW Website （in Japanese Only） |