GHS Classification Result

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GENERAL INFORMATION

Item Information
CAS number 41935-39-1
Chemical name Bis(2-phenoxyethyl) peroxydicarbonate
Substance ID 23A5109
Fiscal year of classification conducted FY2011
Classifier(s) (Ministries) Ministry of Health, Labour and Welfare （MHLW）, Ministry of the Environment （MOE）
New/Revised New
Download in Excel format Excel file

REFERENCE INFORMATION

Item Information
Guidance used for classification (External link) Physical Hazards & Health Hazards: GHS Classification Guidance by the Japanese Government （July, 2010）
Environmental Hazards: UN GHS Document （4th revised edition）
Definitions / Abbreviations (Excel file) Definitions / Abbreviations
Model Label by MHLW (External link) MHLW Website （in Japanese Only）
Model SDS by MHLW (External link) MHLW Website （in Japanese Only）
OECD/eChemPortal (External link) eChemPortal

PHYSICAL HAZARDS

Hazard class Classification Symbol
Signal word 		Hazard statement Precautionary statement Rationale for the classification
1 Explosives Classification not possible - - - This substance is classified in Class 5.2 Subsidiary risk 1 (UN3102 ORGANIC PEROXIDE TYPE B, SOLID) in UNRTDG (16th, 2009) and corresponds to Explosives, but the classification in divisions is not possible due to no detail test data.
Besides, the oxygen balance calculation is -119.23.
2 Flammable gases （including chemically unstable gases） Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
3 Aerosols Not applicable - - - Not an aerosol product.
4 Oxidizing gases Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
5 Gases under pressure Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
6 Flammable liquids Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
7 Flammable solids Classification not possible - - - No data.
8 Self-reactive substances and mixtures Not applicable - - - It is classified as organic peroxides.
9 Pyrophoric liquids Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
10 Pyrophoric solids Classification not possible - - - No data.
11 Self-heating substances and mixtures Classification not possible - - - No established test method suitable for solid substances with a melting point of 140 degrees C or lower.
12 Substances and mixtures which, in contact with water, emit flammable gases Not applicable - - - Not containing metals or semimetals (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
13 Oxidizing liquids Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
14 Oxidizing solids Classification not possible - - - An organic compound that contains oxygen some of which are chemically bonded to oxygen atoms mutually other than carbon, but the classification is not possible due to no data.
15 Organic peroxides Type B


Danger
 H241
 P411+P235
P210
P220
P234
P280
P410
P420
P501
 The substance whose concentration is > 85 to 100 % is classified in Class 5.2 (UN3102 ORGANIC PEROXIDE TYPE B,) in UNRTDG.
16 Corrosive to metals Classification not possible - - - No data.

HEALTH HAZARDS

Hazard class Classification Symbol
Signal word 		Hazard statement Precautionary statement Rationale for the classification
1 Acute toxicity （Oral） Not classified - - - On the basis of an LD50 value of > 20000 mg/kg bw for rats (PATTY (5th, 2001)), it was classified as "Not classified."
1 Acute toxicity （Dermal） Not classified - - - On the basis of an LD50 value of > 20000 mg/kg bw for rats (PATTY (5th, 2001)), it was classified as "Not classified."
1 Acute toxicity （Inhalation: Gases） Not applicable - - - It is a solid at normal temperatures (UNRTDG (16th, 2009)).
1 Acute toxicity （Inhalation: Vapours） Classification not possible - - - No data.
1 Acute toxicity （Inhalation: Dusts and mists） Classification not possible - - - No data.
2 Skin corrosion/irritation Classification not possible - - - No data.
3 Serious eye damage/eye irritation Classification not possible - - - It was classified as "Classification not possible" because a test using rats reports "mild irritant" (PATTY (5th, 2001)) details of which are unknown.
4 Respiratory sensitization Classification not possible - - - No data.
4 Skin sensitization Classification not possible - - - No data.
5 Germ cell mutagenicity Classification not possible - - - The classification is not possible due to no in vivo test data.
Besides, a negative result in an Ames test in an in vitro test is obtained (PATTY (5th, 2001)).
6 Carcinogenicity Classification not possible - - - No data.
7 Reproductive toxicity Classification not possible - - - No data.
8 Specific target organ toxicity - Single exposure Classification not possible - - - No data.
9 Specific target organ toxicity - Repeated exposure Classification not possible - - - No data.
10 Aspiration hazard Classification not possible - - - No data.

ENVIRONMENTAL HAZARDS

Hazard class Classification Symbol
Signal word 		Hazard statement Precautionary statement Rationale for the classification
11 Hazardous to the aquatic environment （Acute） Classification not possible - - - No data.
11 Hazardous to the aquatic environment （Long-term） Classification not possible - - - No data.
12 Hazardous to the ozone layer Classification not possible - - - This substance is not listed in Annexes to the Montreal Protocol.


NOTES:
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.



Updated date:
2016/7/29 Addition of Rationale for the classification

List of GHS Classification Results