GHS Classification Result

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GENERAL INFORMATION
Item Information
CAS RN 124-73-2
Chemical Name 1,2-Dibromo-1,1,2,2-tetrafluoroethane (synonym: Halone-2402)
Substance ID H27-B-20-METI, M-032B_P
Classification year (FY) FY2015
Ministry who conducted the classification Ministry of Economy, Trade and Industry (METI)/Ministry of the Environment (MOE)
New/Revised New
Classification result in other fiscal year  
Download of Excel format Excel file

REFERENCE INFORMATION
Item Information
Guidance used for the classification (External link) GHS Classification Guidance for the Japanese Government (FY2013 revised edition (Ver. 1.1))
UN GHS document (External link) UN GHS document
Definitions/Abbreviations (Excel file) Definitions/Abbreviations
Model Label by MHLW (External link)  
Model SDS by MHLW (External link)  
OECD/eChemPortal (External link) eChemPortal

PHYSICAL HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
1 Explosives Not applicable
-
-
- - There are no chemical groups present in the molecule associated with explosive properties.
2 Flammable gases (including chemically unstable gases) Not applicable
-
-
- - "Liquids" according to GHS definition.
3 Aerosols Not applicable
-
-
- - Not an aerosol product.
4 Oxidizing gases Not applicable
-
-
- - "Liquids" according to GHS definition.
5 Gases under pressure Not applicable
-
-
- - "Liquids" according to GHS definition.
6 Flammable liquids Not classified
-
-
- - It is nonflammable. (HSDB (Access on October 2015))
7 Flammable solids Not applicable
-
-
- - "Liquids" according to GHS definition.
8 Self-reactive substances and mixtures Not applicable
-
-
- - There are no chemical groups present in the molecule associated with explosive or self-reactive properties.
9 Pyrophoric liquids Not classified
-
-
- - It is nonflammable. (HSDB (Access on October 2015))
10 Pyrophoric solids Not applicable
-
-
- - "Liquids" according to GHS definition.
11 Self-heating substances and mixtures Classification not possible
-
-
- - No established test method suitable for liquid substances.
12 Substances and mixtures which, in contact with water, emit flammable gases Not applicable
-
-
- - Not containing metals or metalloids (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
13 Oxidizing liquids Not applicable
-
-
- - It is an organic compound which does not contain oxygen or chlorine but contains fluorine, and the fluorine is not chemically bonded to the elements other than carbon or hydrogen.
14 Oxidizing solids Not applicable
-
-
- - "Liquids" according to GHS definition.
15 Organic peroxides Not applicable
-
-
- - It is an organic compound that does not contain bivalent -O-O- structure in the molecule.
16 Corrosive to metals Classification not possible
-
-
- - No established test method suitable for a liquid with a low boiling point.

HEALTH HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
1 Acute toxicity (Oral) Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
1 Acute toxicity (Dermal) Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
1 Acute toxicity (Inhalation: Gases) Not applicable
-
-
- - "Liquids" according to GHS definition.
1 Acute toxicity (Inhalation: Vapours) Classification not possible
-
-
- - The classification is not possible due to lack of data. Other than a reported LC50 value (2 hours) of 850 to 950 g/m3 (converted to a 4-hour equivalent: 56,600 to 63,200 ppm) for rats (GESTIS (Access on November 2015)), an LC50 value (4 hours) of 300,000 mg/m3 (28,200 ppm) for mice and an LD50 value (4-hour inhalation) of 584,000 mg/kg for rats were reported (https://www.agasamericas.com/wp-content/uploads/2015/01/Halon-2402-SDS.pdf), but these data were not adopted for the classification due to insufficient reliability. Besides, these toxicity values correspond to "Not classified." A reference value in the unit of ppm was applied as vapour without mist because the LC50 values are lower than 90% of the saturated vapour pressure concentration (427,443 ppm).
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
2 Skin corrosion/irritation Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
3 Serious eye damage/eye irritation Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
4 Respiratory sensitization Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
4 Skin sensitization Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
5 Germ cell mutagenicity Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
6 Carcinogenicity Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
7 Reproductive toxicity Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
8 Specific target organ toxicity - Single exposure Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
9 Specific target organ toxicity - Repeated exposure Classification not possible
-
-
- - Due to lack of data, the classification is not possible.
10 Aspiration hazard Classification not possible
-
-
- - The classification is not possible due to lack of data. Besides, kinematic viscosity is calculated to be 0.335 mm2/sec (25 degrees C) from numerical data (viscosity: 0.72 mPa.s (25 degrees C), density: 2.149 g/cm3 (25 degrees C)) listed in HSDB (Access on October 2015).

ENVIRONMENTAL HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
11 Hazardous to the aquatic environment (Acute) Classification not possible
-
-
- - No data.
11 Hazardous to the aquatic environment (Long-term) Classification not possible
-
-
- - No data.
12 Hazardous to the ozone layer Classification not possible
-
-
- - No data.


NOTE:
* A blank or "-" in a cell of classification denotes that the classification of the hazard class was not conducted.
* Hazard_statement_and/or_Precautionary_statement will show when hovering the mouse over a code of Hazard_statement_and/or_Precautionary_statement.
Hazard_statement_and/or_Precautionary_statement are also provided in the Excel file.
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government,
and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.
* Codes assigned to each of the hazard statements and codes for each of the precautionary statement are
based on the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) in United Nations.

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