GHS Classification Result
GENERAL INFORMATION
REFERENCE INFORMATION
PHYSICAL HAZARDS
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS
NOTE:
GENERAL INFORMATION
| Item | Information |
|---|---|
| CAS RN | - |
| Chemical Name | Reaction products of 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate [DOTE] and 2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4-octyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate [MOTE] |
| Substance ID | H27-A-030/C-060A_P |
| Classification year (FY) | FY2015 |
| Ministry who conducted the classification | Ministry of Health, Labour and Welfare (MHLW)/Ministry of the Environment (MOE) |
| New/Revised | New |
| Classification result in other fiscal year | |
| Download of Excel format | Excel file |
REFERENCE INFORMATION
| Item | Information |
|---|---|
| Guidance used for the classification (External link) | GHS Classification Guidance for the Japanese Government (FY2013 revised edition (Ver. 1.1)) |
| UN GHS document (External link) | UN GHS document |
| Definitions/Abbreviations (Excel file) | Definitions/Abbreviations |
| Model Label by MHLW (External link) | |
| Model SDS by MHLW (External link) | |
| OECD/eChemPortal (External link) | eChemPortal |
| Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | |
|---|---|---|---|---|---|---|
| 1 | Explosives | Not applicable |
- |
- | - | There are no chemical groups present in the molecule associated with explosive properties. |
| 2 | Flammable gases (including chemically unstable gases) | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 3 | Aerosols | Not applicable |
- |
- | - | Not an aerosol product. |
| 4 | Oxidizing gases | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 5 | Gases under pressure | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 6 | Flammable liquids | Not classified |
- |
- | - | (DOTE) A flash point is 117 degrees C (closed cup) (SIDS (2009)). (MOTE) A flash point is 156 degrees C (closed cup) (GESTIS (Access on July 2015)). |
| 7 | Flammable solids | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 8 | Self-reactive substances and mixtures | Not applicable |
- |
- | - | There are no chemical groups present in the molecule associated with explosive or self-reactive properties. |
| 9 | Pyrophoric liquids | Classification not possible |
- |
- | - | Due to no data, the classification is not possible. |
| 10 | Pyrophoric solids | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 11 | Self-heating substances and mixtures | Classification not possible |
- |
- | - | No established test method suitable for liquid substances. |
| 12 | Substances and mixtures which, in contact with water, emit flammable gases | Classification not possible |
- |
- | - | Due to no data, the classification is not possible. |
| 13 | Oxidizing liquids | Not applicable |
- |
- | - | It is an organic compound which does not contain fluorine or chlorine but contains oxygen, and the oxygen is not chemically bonded to the elements other than carbon or hydrogen. |
| 14 | Oxidizing solids | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 15 | Organic peroxides | Not applicable |
- |
- | - | It is an organic compound that does not contain bivalent -O-O- structure in the molecule. |
| 16 | Corrosive to metals | Classification not possible |
- |
- | - | Due to no data, the classification is not possible. |
| Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | |
|---|---|---|---|---|---|---|
| 1 | Acute toxicity (Oral) | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| 1 | Acute toxicity (Dermal) | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| 1 | Acute toxicity (Inhalation: Gases) | Not applicable |
- |
- | - | "Liquids" according to GHS definition. |
| 1 | Acute toxicity (Inhalation: Vapours) | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| 1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| 2 | Skin corrosion/irritation | Classification not possible |
- |
- | - | The classification is not possible due to lack of data. Besides, it is reported for DOTE that in a skin irritation test using rabbits (OECD TG404, GLP compliance), after the application of a solution containing 90% DOTE (10% Octyltin tris (2-EHMA)), slight scaling was observed but resolved within ten days (SIDS (2009)). |
| 3 | Serious eye damage/eye irritation | Classification not possible |
- |
- | - | The classification is not possible due to lack of data. Besides, it is reported for DOTE that in an eye irritation test (OECD TG405, GLP compliance) using rabbits, after the application of 0.1 mL undiluted DOTE (> 98%) into conjunctival sac for 96 hours, irritation was observed in the conjunctiva, but it resolved within four days (SIDS (2009)). |
| 4 | Respiratory sensitization | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| 4 | Skin sensitization | Category 1 |
 Warning |
H317 | P302+P352 P333+P313 P362+P364 P261 P272 P280 P321 P501 |
There are no data on this substance itself. However, this substance is a mixture containing 10 to 80% DOTE (ECHA's Report on Proposal for Identification of a Substance of Very High Concern (2014)), and it can be classified as a mixture containing DOTE. It is reported that in a sensitization test (OECD TG 406, GLP compliance) in which a solution containing 90% DOTE (10% Octyltin tris (2-EHMA)) was applied to guinea pigs, a positive reaction was observed (SIDS (2009)). Besides, it is reported that in a sensitization test (OECD TG 406, GLP compliance) using a solution containing DOTE (DOTE 70%, Octyltin tris (2-EHMA) 30%), a clear positive reaction was found (SIDS (2009)). The substance was classified in Category 1 from the above results. |
| 5 | Germ cell mutagenicity | Classification not possible |
- |
- | - | There are no data on this substance itself. However, this substance is a mixture containing 10 to 80% DOTE, and it was classified as a mixture containing DOTE. The classification result is the same as DOTE, and the classification is not possible due to lack of data. There are no in vivo data, and as for in vitro, negative and positive data were reported in a bacterial reverse mutation test (SIDS (2009)). |
| 6 | Carcinogenicity | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| 7 | Reproductive toxicity | Category 1B |
 Danger |
H360 | P308+P313 P201 P202 P280 P405 P501 |
There are no data on this substance itself. However, this substance is a mixture containing 10 to 80% DOTE (ECHA's Report on Proposal for Identification of a Substance of Very High Concern (2014)), and it can be classified as a mixture containing DOTE. This substance was also classified in Category 1B similarly to DOTE. Besides, EU classified this substance (reaction mass of DOTE and MOTE) in SVHC as "Repr.1B" (ECHA (Access on July 2015)). |
| 8 | Specific target organ toxicity - Single exposure | Category 3 (Narcotic effects) |
Warning |
H336 | P304+P340 P403+P233 P261 P271 P312 P405 P501 |
There are no data on this substance itself. However, this substance is a mixture containing 10 to 80% DOTE, and it was classified as a mixture containing DOTE. The classification result is the same as DOTE and Category 3 (narcotic effects). |
| 9 | Specific target organ toxicity - Repeated exposure | Category 1 (immune system), Category 2 (liver, kidney) |
Danger Warning |
H372 H373 |
P260 P264 P270 P314 P501 |
There are no data on this substance itself. However, this substance is a mixture containing 10 to 80% DOTE, and it was classified as a mixture containing DOTE. The classification result is the same as DOTE and Category 1 (immune system), Category 2 (liver, kidney). |
| 10 | Aspiration hazard | Classification not possible |
- |
- | - | Due to lack of data, the classification is not possible. |
| Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | |
|---|---|---|---|---|---|---|
| 11 | Hazardous to the aquatic environment (Acute) | Classification not possible |
- |
- | - | No data. |
| 11 | Hazardous to the aquatic environment (Long-term) | Classification not possible |
- |
- | - | No data. |
| 12 | Hazardous to the ozone layer | Classification not possible |
- |
- | - | No data. |
NOTE:
| * A blank or "-" in a cell of classification denotes that the classification of the hazard class was not conducted. * Hazard_statement_and/or_Precautionary_statement will show when hovering the mouse over a code of Hazard_statement_and/or_Precautionary_statement. Hazard_statement_and/or_Precautionary_statement are also provided in the Excel file. * Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users. * This is a provisional English translation of classification results and is subject to revision without notice. * The responsibility for any resulting GHS labelling and SDS referenced from this site is with users. * Codes assigned to each of the hazard statements and codes for each of the precautionary statement are based on the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) in United Nations. |