GHS Classification Result

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GENERAL INFORMATION
Item Information
CAS RN 1328-53-6
Chemical Name Phthalocyanine Green
Substance ID H28-A-044, C-095A
Classification year (FY) FY2016
Ministry who conducted the classification Ministry of Health, Labour and Welfare (MHLW)/Ministry of the Environment (MOE)
New/Revised New
Classification result in other fiscal year  
Download of Excel format Excel file

REFERENCE INFORMATION
Item Information
Guidance used for the classification (External link) GHS Classification Guidance for the Japanese Government (FY2013 revised edition (Ver. 1.1))
UN GHS document (External link) UN GHS document
Definitions/Abbreviations (Excel file) Definitions/Abbreviations
Model Label by MHLW (External link) MHLW Website (in Japanese Only)
Model SDS by MHLW (External link) MHLW Website (in Japanese Only)
OECD/eChemPortal (External link) eChemPortal

PHYSICAL HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
1 Explosives Not applicable
-
-
- -  There are no chemical groups associated with explosive properties present in the molecule.
2 Flammable gases (including chemically unstable gases) Not applicable
-
-
- -  Solid (GHS definition).
3 Aerosols Not applicable
-
-
- -  Not aerosol products.
4 Oxidizing gases Not applicable
-
-
- -  Solid (GHS definition).
5 Gases under pressure Not applicable
-
-
- -  Solid (GHS definition).
6 Flammable liquids Not applicable
-
-
- -  Solid (GHS definition).
7 Flammable solids Classification not possible
-
-
- -  No data available. Besides, it is written that it is poorly flammable (GESTIS (Access on July 2016)).
8 Self-reactive substances and mixtures Not applicable
-
-
- -  There are no chemical groups present in the molecule associated with explosive or self-reactive properties.
9 Pyrophoric liquids Not applicable
-
-
- -  Solid (GHS definition).
10 Pyrophoric solids Classification not possible
-
-
- -  No data available. Besides, it is written that it is poorly flammable (GESTIS (Access on July 2016)).
11 Self-heating substances and mixtures Classification not possible
-
-
- -  No data available. Besides, it is written that it is poorly flammable (GESTIS (Access on July 2016)).
12 Substances and mixtures which, in contact with water, emit flammable gases Not classified
-
-
- -  The substance can be purified by reprecipitation in water after dissolving in concentrated sulfuric acid. From the manufacturing method, it is estimated that it does not react vigorously with water.
13 Oxidizing liquids Not applicable
-
-
- -  Solid (GHS definition).
14 Oxidizing solids Not applicable
-
-
- -  The substance is an organic compound containing chlorine (but not fluorine or oxygen) which is chemically bonded only to carbon or hydrogen.
15 Organic peroxides Not applicable
-
-
- -  Organic compounds containing no bivalent -O-O- structure in the molecule
16 Corrosive to metals Classification not possible
-
-
- -  Test methods applicable to solid substances are not available.

HEALTH HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
1 Acute toxicity (Oral) Not classified
-
-
- -  Based on the LD50 value of >2,000 mg/kg for rats (OECD TG401) (JECDB (Access on September 2016), SIDS (2010)), the substance was classified as "Not classified."
1 Acute toxicity (Dermal) Classification not possible
-
-
- -  Classification not possible due to lack of data.
1 Acute toxicity (Inhalation: Gases) Not applicable
-
-
- -  Solid (GHS definition)
1 Acute toxicity (Inhalation: Vapours) Not applicable
-
-
- -  Solid (GHS definition)
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible
-
-
- -  Classification not possible due to lack of data.
2 Skin corrosion/irritation Not classified
-
-
- -  In a skin irritation study (occlusive 24-hour exposure) using rabbits in accordance with US guideline (Federal Register 38, No. 187, Section 1500.41, S. 27019, (1973)), very slight irritation (primary irritation index (PII) of 1.1) was observed, but the irritation was recovered after 7 days (SIDS (2010)).
 The substance was classified as "Not classified" because it was evaluated that this substance is not irritating to the skin (SIDS (2010)).
3 Serious eye damage/eye irritation Not classified
-
-
- -  In a rabbit eye irritation study in accordance with the US guideline (equivalent to OECD TG 405), very slight irritation of the cornea (eye irritation index 1.8) was observed but disappeared after 3 days (SIDS (2010)). The substance was classified as "Not classified" because it is concluded this substance is not irritating to the eyes (SIDS (2010)).
4 Respiratory sensitization Classification not possible
-
-
- -  Classification not possible due to lack of data.
4 Skin sensitization Classification not possible
-
-
- -  Classification not possible due to lack of data. Besides, it is reported that it was negative in the skin sensitization test using guinea pigs (SIDS (2010)), but details were unknown. It is reported that an art painter exposed to this substance during painting by a special technique showed positive in a patch test, however, it is considered to be an isolated case (SIDS (2010)). Therefore, this information was not adopted for the evidence of classification.
5 Germ cell mutagenicity Classification not possible
-
-
- -  Classification not possible due to lack of data.
6 Carcinogenicity Classification not possible
-
-
- -  Classification not possible due to lack of data.
7 Reproductive toxicity Classification not possible
-
-
- -  Classification not possible due to lack of data.
8 Specific target organ toxicity - Single exposure Classification not possible
-
-
- -  Classification not possible due to lack of data.
 There is no single exposure data of this substance in humans.
 As for experimental animals, it is reported that in a single oral administration to rats at 5,000 mg/kg, which is beyond the range of Category 2, dyspnea, apathy and poor general condition were observed (SIDS (2010)).
9 Specific target organ toxicity - Repeated exposure Classification not possible
-
-
- -  There is no information on humans.
 As for experimental animals, in a 28-day repeated dose toxicity study using rats given by gavage, and 90-day repeated dose toxicity studies using rats or mice given by feeding, no effects were observed within the range of Category 2 (SIDS (2010)).
 However, the substance was classified as "Classification not possible" due to lack of data because there is no information etc. by other routes.
10 Aspiration hazard Classification not possible
-
-
- -  Classification not possible due to lack of data.

ENVIRONMENTAL HAZARDS
Hazard class Classification Pictogram
Signal word
Hazard statement
(code)
Precautionary statement
(code)
Rationale for the classification
11 Hazardous to the aquatic environment (Acute) Not classified
-
-
- -  From 48-hour EC50 = 153.6 mg/L for crustacea (Daphnia magna) and 96-hour LC50 = 355.6 mg/L for fish (Oncorhynchus mykiss) (both SIDS, 2010), it was classified as "Not classified."
11 Hazardous to the aquatic environment (Long-term) Not classified
-
-
- -  If chronic toxicity data are used, then it is classified as "Not classified" due to 21-day NOEC >= 1 mg/L for crustacea (Daphnia magna) (SIDS, 2010), though no data obtained on rapid degradability.
 If acute toxicity data are used for a trophic level for which chronic toxicity data are not obtained, then it is classified as "Not classified" because it is estimated to be low bioaccumulative (BCF was (0.51)-4.8, < 2.1-74 when test concentration was set to be 100 ppb and 10 ppb (Biodegradation and Bioconcentration Results of Existing Chemical Substances under the Chemical Substances Control Law, 1980)), and its 96-hour LC50 = 355.6 mg/L for fish (Oncorhynchus mykiss) (SIDS, 2010), though no data obtained on rapid degradability.
 It was classified as "Not classified" from the above results.
12 Hazardous to the ozone layer Classification not possible
-
-
- -  No data available.


NOTE:
* A blank or "-" in a cell of classification denotes that the classification of the hazard class was not conducted.
* Hazard_statement_and/or_Precautionary_statement will show when hovering the mouse over a code of Hazard_statement_and/or_Precautionary_statement.
Hazard_statement_and/or_Precautionary_statement are also provided in the Excel file.
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government,
and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.
* Codes assigned to each of the hazard statements and codes for each of the precautionary statement are
based on the Globally Harmonized System of Classification and Labelling of Chemicals (GHS) in United Nations.

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