Item | Information |
---|---|
CAS RN | 10045-94-0 |
Chemical Name | mercury dinitrate |
Substance ID | m-nite-10045-94-0_v1 |
Download of Excel format | Excel file |
Item | Information |
---|---|
Guidance used for the classification (External link) | To Guidance List |
UN GHS document (External link) | To UN GHS document |
FAQ(GHS classification results by the Japanese Government) | To FAQ |
List of Information Sources (Excel file) | List of Information Sources |
List of Definitions/Abbreviations | Definitions/Abbreviations |
Sample Label by MHLW (External link) | MHLW Website (in Japanese Only) |
Sample SDS by MHLW (External link) | MHLW Website (in Japanese Only) |
OECD/eChemPortal (External link) | To OECD/eChemPortal (External link) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Explosives | Not classified |
- |
- | - | Not Classified because of UNRTDG No. 1625, Class: 6.1, II and not explosive solely, though the substance contains N-O bonds as chemical groups associated with explosive properties present. (Reactions of the substance with several kinds of compounds such as acetylenes or ethanols lead to explosive products.) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
2 | Flammable gases | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
3 | Aerosols | Not classified (Not applicable) |
- |
- | - | Not aerosol products | FY2006 | GHS Classification Manual (10 Feb, 2006) |
4 | Oxidizing gases | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
5 | Gases under pressure | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
6 | Flammable liquids | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
7 | Flammable solids | Not classified |
- |
- | - | Non-combustible (ICSC (J) (2000)) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
8 | Self-reactive substances and mixtures | Not classified |
- |
- | - | Not classified based on UNRTDG No. 1625, Class: 6.1, PGII | FY2006 | GHS Classification Manual (10 Feb, 2006) |
9 | Pyrophoric liquids | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
10 | Pyrophoric solids | Not classified |
- |
- | - | Non-combustible (ICSC (J), 2000) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
11 | Self-heating substances and mixtures | Not classified |
- |
- | - | Not combustible (ICSC(J) (2000)) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified |
- |
- | - | Stable to wate (HSDB, 2003) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
13 | Oxidizing liquids | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
14 | Oxidizing solids | Not classified |
- |
- | - | Not classified because of UNRTDG No. 1625, Class: 6.1, PGII, though it is a strong oxidizing agent (ICSC(J), 2000; Sax, 11th, 2004). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
15 | Organic peroxides | Not classified (Not applicable) |
- |
- | - | Inorganic compound | FY2006 | GHS Classification Manual (10 Feb, 2006) |
16 | Corrosive to metals | Classification not possible |
- |
- | - | Test methods applicable to solid substances are not available. | FY2006 | GHS Classification Manual (10 Feb, 2006) |
17 | Desensitized explosives | - |
- |
- | - | - | - | - |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Category 2 |
Danger |
H300 | P301+P310 P264 P270 P321 P330 P405 P501 |
SPECIES: Rat; ENDPOINT: LD50;VALUE:26mg/kg; REFERENCE SOURCE: RTECS (2005) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
1 | Acute toxicity (Dermal) | Category 2 |
Danger |
H310 | P302+P352 P361+P364 P262 P264 P270 P280 P310 P321 P405 P501 |
It is based on rat dermal LD50= 75mg/kg (RTECS, 2005). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
1 | Acute toxicity (Inhalation: Gases) | Not classified (Not applicable) |
- |
- | - | Solid (GHS definition) | FY2006 | GHS Classification Manual (10 Feb, 2006) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible |
- |
- | - | No data available | FY2006 | GHS Classification Manual (10 Feb, 2006) |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible |
- |
- | - | No data available | FY2006 | GHS Classification Manual (10 Feb, 2006) |
2 | Skin corrosion/irritation | Category 1 |
Danger |
H314 | P301+P330+P331 P303+P361+P353 P305+P351+P338 P304+P340 P260 P264 P280 P310 P321 P363 P405 P501 |
It was set as Category 1A-1C from the description with the possibility which indicated skin corrosivities (ICSC, 2000) and skin irritation to humans (DFGOT, vol.15, 2001[as inorganic mercury compounds]; HSFS, 1993). [view] When subdivision needs to be performed, it is desirable to be seto as Category 1A from a viewpoint of safety. |
FY2006 | GHS Classification Manual (10 Feb, 2006) |
3 | Serious eye damage/eye irritation | Category 1 |
Danger |
H318 | P305+P351+P338 P280 P310 |
There is the descripiton of oculo corrosiveness (ICSC, 2000), and it is classified into Category 1 in description of skin corrosivenesses. So it was classified into Category 1. | FY2006 | GHS Classification Manual (10 Feb, 2006) |
4 | Respiratory sensitization | Classification not possible |
- |
- | - | No data available | FY2006 | GHS Classification Manual (10 Feb, 2006) |
4 | Skin sensitization | Category 1 |
Warning |
H317 | P302+P352 P333+P313 P362+P364 P261 P272 P280 P321 P501 |
Metal mercury and inorganic mercury compound (as Hg) were set to Category 1 from description with the possibility which there is skin sensitization (MAK/BAT, 2005; DFGOT, vol.15, 2001), and shows skin sensitization in ICSC (2000). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
5 | Germ cell mutagenicity | Category 2 |
Warning |
H341 | P308+P313 P201 P202 P280 P405 P501 |
In ATSDR (1999), since it estimated that mercury and mercury compounds induced chromosomal abnormality to the animal somatic cell in an in vivo, they were set to Category 3. | FY2006 | GHS Classification Manual (10 Feb, 2006) |
6 | Carcinogenicity | Not classified |
- |
- | - | As inorganic mercury compounds, it was out of the Category. Since it is classified into IARC Group 3 (IARC, 58, 1993) and ACGIH A4 (ACGIH-TLV, 2004). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
7 | Reproductive toxicity | Category 2 |
Warning |
H361 | P308+P313 P201 P202 P280 P405 P501 |
Since the effect on generating (California EPA, Proposition 65 List of Chemicals, 2005) and reproductive (ACGIH-TLV, 2004) was indicated as mercury and mercury compounds or inorganic mercuries, it was considered as Category 2. | FY2006 | GHS Classification Manual (10 Feb, 2006) |
8 | Specific target organ toxicity - Single exposure | Category 1 (kidney), Category 2 (respiratory organs) |
Danger Warning |
H370 H371 |
P308+P311 P260 P264 P270 P321 P405 P501 |
The substance was classified as Category 1 (kidneys) and Category 2 (respiratory organs) based on the reports concerning humans in Priority 1 documents that the target organs of the substance in the inorganic mercury compound are the kidneys (DFGOT, vol.15, 2001), and on the reports of the effects on the kidneys and airways corrosivity or respiratory organ irritant properties in Priority 2 documents (ICSC, 2000; HSFS, 1993; SITTIG, 4th, 2002). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
9 | Specific target organ toxicity - Repeated exposure | Category 1 (central nervous system, kidney) |
Danger |
H372 | P260 P264 P270 P314 P501 |
Since in Priority 1 document, the effect on the central nervous systems and the kidneyto humans by inorganic mercury compounds was described (ACGIH-TLV, 2004;EHC, 118, 1991) , and the effect on the nervous system and the kidney by the product was indicated in Priority 2 document (ICSC, 2000;SITTIG, 4th, 2002), it was classified into Category 1 (a central nervous systems, the kidney). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
10 | Aspiration hazard | Classification not possible |
- |
- | - | No data available | FY2006 | GHS Classification Manual (10 Feb, 2006) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment Short term (Acute) | Category 1 |
Warning |
H400 | P273 P391 P501 |
It was classified into Category 1 from 96-hour LC50=33microg/L(mercury (II) nitrate concentration equivalent: 53microg/L) of fishes (Rainbow trout) (EHC86, 1989). | FY2006 | GHS Classification Manual (10 Feb, 2006) |
11 | Hazardous to the aquatic environment Long term (Chronic) | Category 1 |
Warning |
H410 | P273 P391 P501 |
Classified into Category 1, since acute toxicity was Category 1, and it is a metallic compound, behavior in water and bioaccumulative potential are unknown. | FY2006 | GHS Classification Manual (10 Feb, 2006) |
12 | Hazardous to the ozone layer | - |
- |
- | - | - | - | - |
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