Item | Information |
---|---|
CAS RN | 16071-86-6 |
Chemical Name | {5-[(4'-((2,6-Hydroxy-3-((2-hydroxy-5-sulfophenyl)azo)phenyl)azo)(1,1'-biphenyl)-4-yl)azo]salicylato(4-)}cuprate(2-) disodium salt; C.I. Direct Brown 95 |
Substance ID | m-nite-16071-86-6_v1 |
Download of Excel format | Excel file |
Item | Information |
---|---|
Guidance used for the classification (External link) | To Guidance List |
UN GHS document (External link) | To UN GHS document |
FAQ(GHS classification results by the Japanese Government) | To FAQ |
List of Information Sources (Excel file) | List of Information Sources |
List of Definitions/Abbreviations | Definitions/Abbreviations |
Sample Label by MHLW (External link) | MHLW Website (in Japanese Only) |
Sample SDS by MHLW (External link) | MHLW Website (in Japanese Only) |
OECD/eChemPortal (External link) | To OECD/eChemPortal (External link) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Explosives | Not classified (Not applicable) |
- |
- | - | It does not contain chemical groups (aliphatic azo group) associated with explosive properties. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
2 | Flammable gases | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
3 | Aerosols | Not classified (Not applicable) |
- |
- | - | Not aerosol products. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
4 | Oxidizing gases | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
5 | Gases under pressure | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
6 | Flammable liquids | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
7 | Flammable solids | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
8 | Self-reactive substances and mixtures | Not classified (Not applicable) |
- |
- | - | It does not contain chemical groups (aliphatic azo group) associated with explosive properties or those associated with self-reactive properties. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
9 | Pyrophoric liquids | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
10 | Pyrophoric solids | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
11 | Self-heating substances and mixtures | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified |
- |
- | - | There is a product made of this substance dissolved in water. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
13 | Oxidizing liquids | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
14 | Oxidizing solids | Classification not possible |
- |
- | - | It is an organic compound containing oxygen (but not fluorine or chlorine), which is chemically bonded to sulfur. Since no test results based on standardized testing methods are available, classification is not possible. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
15 | Organic peroxides | Not classified (Not applicable) |
- |
- | - | Organic compounds containing no bivalent -O-O- structure | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
16 | Corrosive to metals | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
17 | Desensitized explosives | - |
- |
- | - | - | - | - |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Not classified |
- |
- | - | Since rat LD50 = 12060 mg/kg (RTECS accessed in October 2007), the substance was classified into the "Not classified" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Dermal) | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Inhalation: Gases) | Not classified (Not applicable) |
- |
- | - | Since the substance is a solid, it was classified into the "Not applicable" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
2 | Skin corrosion/irritation | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
3 | Serious eye damage/eye irritation | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
4 | Respiratory sensitization | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
4 | Skin sensitization | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
5 | Germ cell mutagenicity | Classification not possible |
- |
- | - | Both in vivo unscheduled DNA synthesis test using rats and in vitro reverse mutation test using rats gave positive results (RTECS accessed in October 2007). Since no other test results are available, classification is not possible. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
6 | Carcinogenicity | Category 1B |
Danger |
H350 | P308+P313 P201 P202 P280 P405 P501 |
It is rated as "Group 2A" by the IARC (IARC Suppl. 7 (1987)) and "Group 2A" by Japan Society for Occupational Health (Recommendations of Occupational Exposure Limits 2007). Based on these ratings, the substance was classified into Category 1B. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
7 | Reproductive toxicity | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
8 | Specific target organ toxicity - Single exposure | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
9 | Specific target organ toxicity - Repeated exposure | Category 2 (liver, bone marrow, lymphatic system) |
Warning |
H373 | P260 P314 P501 |
In mixed diet administration tests using rats, portal fibrosis in the liver, decreased bone marrow cells, and necrosis of lymphoid cells were noted at doses that fall under Category 2 (IARC vol. 29 (1972)). Based on these results, the substance was classified into Category 2 (liver, bone marrow, and lymphatic system). | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
10 | Aspiration hazard | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment Short term (Acute) | Not classified |
- |
- | - | Since its 96-hour LC50 is > 180 mg/L for fathead minnow (Aquire, 2007), the substance was classified into the "Not classified" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
11 | Hazardous to the aquatic environment Long term (Chronic) | Not classified |
- |
- | - | Its classification for acute toxicity is the "Not classified" category, logPow = -6.53 (SRC 2007), and it has no potential for bioaccumulation. Based on this information, the substance was classified into the "Not classified" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
12 | Hazardous to the ozone layer | - |
- |
- | - | - | - | - |
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