Item | Information |
---|---|
CAS RN | 32055-14-4 |
Chemical Name | Polymer of aniline / formaldehyde / phosgene |
Substance ID | m-nite-32055-14-4_v1 |
Download of Excel format | Excel file |
Item | Information |
---|---|
Guidance used for the classification (External link) | To Guidance List |
UN GHS document (External link) | To UN GHS document |
FAQ(GHS classification results by the Japanese Government) | To FAQ |
List of Information Sources (Excel file) | List of Information Sources |
List of Definitions/Abbreviations | Definitions/Abbreviations |
Sample Label by MHLW (External link) | |
Sample SDS by MHLW (External link) | |
OECD/eChemPortal (External link) | To OECD/eChemPortal (External link) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Explosives | Not classified (Not applicable) |
- |
- | - | There are no chemical groups associated with explosive properties present in the molecule. [Reference Data, etc.] (1) This substance (oligomeric MDI (Methylene diphenyl diisocyanate)) is a mixture consisting of 25-85% of 4,4'-MDI (CAS RN 101-68-8), the major constituent, 5-60% of higher oligomers (structurally close to PMDI (polymeric MDI)), 2,2'-MDI, 2,4'-MDI, and others (Document by the European trade association for producers of diisocyanates and polyols (Accessed Oct. 2020)). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
2 | Flammable gases | Not classified (Not applicable) |
- |
- | - | Liquid (GHS definition) | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
3 | Aerosols | Not classified (Not applicable) |
- |
- | - | Not aerosol products. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
4 | Oxidizing gases | Not classified (Not applicable) |
- |
- | - | Liquid (GHS definition) | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
5 | Gases under pressure | Not classified (Not applicable) |
- |
- | - | Liquid (GHS definition) | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
6 | Flammable liquids | Classification not possible |
- |
- | - | No data available. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
7 | Flammable solids | Not classified (Not applicable) |
- |
- | - | Liquid (GHS definition) | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
8 | Self-reactive substances and mixtures | Not classified (Not applicable) |
- |
- | - | There are no chemical groups present in the molecule associated with explosive or self-reactive properties. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
9 | Pyrophoric liquids | Classification not possible |
- |
- | - | No data available. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
10 | Pyrophoric solids | Not classified (Not applicable) |
- |
- | - | Liquid (GHS definition) | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
11 | Self-heating substances and mixtures | Classification not possible |
- |
- | - | Classification is not possible because test methods applicable to liquid substances are not available. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified (Not applicable) |
- |
- | - | The chemical structure of the substance does not contain metals or metalloids (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At). | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
13 | Oxidizing liquids | Not classified (Not applicable) |
- |
- | - | The substance is an organic compound containing oxygen (but not fluorine or chlorine) which is chemically bonded only to carbon or hydrogen. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
14 | Oxidizing solids | Not classified (Not applicable) |
- |
- | - | Liquid (GHS definition) | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
15 | Organic peroxides | Not classified (Not applicable) |
- |
- | - | Organic compounds containing no bivalent -O-O- structure in the molecule. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
16 | Corrosive to metals | Classification not possible |
- |
- | - | No data available. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
17 | Desensitized explosives | Not classified (Not applicable) |
- |
- | - | There are no chemical groups associated with explosive properties present in the molecule. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Classification not possible |
- |
- | - | [Rationale for the Classification] This substance was classified as a mixture consisting of >= 25% of 4,4'-MDI and >= 10% of PMDI from (1). It corresponds to "Not classified" by applying classification by the additivity formula in JIS Z7252:2019 from (2), (3), supposing that acute toxicity estimates (ATE) of 4,4'-MDI and PMDI, the constituents of this substance are > 10,000 mg/kg, and regarding that the toxicity of constituents whose ATE is unknown is equal to that of constituents whose ATE is known. However, because toxicity is unknown for 65% constituents of a mixture, and the contents of those with known ATE are low, the classification is not possible. [Evidence Data] (1) This substance (oligomeric MDI (Methylene diphenyl diisocyanate)) is a mixture containing 25-85% of 4,4'-MDI (CAS RN 101-68-8), the major constituent, 5-60% of higher oligomers (structurally close to PMDI (polymeric MDI)), 2,2'-MDI, 2,4'-MDI, and others (Document by the European trade association for producers of diisocyanates and polyols (Accessed Oct. 2020)). (2) LD50 for rats for 4,4'-MDI, >= 25% of which is contained in this substance: 31,600 mg/kg (CICAD 27 (2000)) (GHS classification result in FY2015). (3) LD50 for rats (males) for PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance: > 10,000 mg/kg (GHS classification result in FY2020) |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
1 | Acute toxicity (Dermal) | Classification not possible |
- |
- | - | [Rationale for the Classification] It corresponds to "Not classified" by applying classification by the additivity formula in JIS Z7252:2019 from (1), (2), supposing that acute toxicity estimates (ATE) of PMDI, the constituent of this substance is > 9,400 mg/kg, and regarding that the toxicity of constituents whose ATE is unknown is equal to that of constituents whose ATE is known. However, because toxicity is unknown for 65% constituents of a mixture, and the contents of those with known ATE are low, the classification is not possible. [Evidence Data] (1) 4,4'-MDI, >= 25% of which is contained in this substance, was classified as "Classification not possible" for this hazard class (GHS classification result in FY2015). (2) LD50 for rabbits for PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance: > 9,400 mg/kg (GHS classification result in FY2020) |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
1 | Acute toxicity (Inhalation: Gases) | Not classified |
- |
- | - | [Rationale for the Classification] Liquid (GHS definition). It was classified as "Not classified." |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible |
- |
- | - | [Rationale for the Classification] Classification not possible due to lack of data. |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
1 | Acute toxicity (Inhalation: Dusts and mists) | Category 2 |
Danger |
H330 | P304+P340 P403+P233 P260 P271 P284 P310 P320 P405 P501 |
[Rationale for the Classification] It was classified in Category 2 by applying classification by the additivity formula in JIS Z7252:2019 from (1), (2), supposing that acute toxicity estimates (ATE) of 4,4'-MDI and PMDI, the constituents of this substance, is 0.05 mg/L, and regarding that the toxicity of constituents whose ATE is unknown is equal to that of constituents whose ATE is known. [Evidence Data] (1) 4,4'-MDI, >= 25% of which is contained in this substance, was classified in Category 2 for this hazard class (GHS classification result in FY2015). (2) PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance, was classified in Category 2 for this hazard class (GHS classification in FY2020) |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
2 | Skin corrosion/irritation | Category 2 |
Warning |
H315 | P302+P352 P332+P313 P362+P364 P264 P280 P321 |
[Rationale for the Classification] It was classified in Category 2 by applying the additivity formula in JIS Z7252:2019 from (1), (2). [Evidence Data] (1) 4,4'-MDI, >= 25% of which is contained in this substance, was classified in Category 2 for this hazard class (GHS classification in FY2015). (2) PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance, was classified as "Classification not possible" for this hazard class (GHS classification in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
3 | Serious eye damage/eye irritation | Category 2 |
Warning |
H319 | P305+P351+P338 P337+P313 P264 P280 |
[Rationale for the Classification] It was classified in Category 2 by applying the additivity formula in JIS Z7252:2019 from (1), (2). [Evidence Data] (1) 4,4'-MDI, >= 25% of which is contained in this substance, was classified in Category 2B for this hazard class (GHS classification in FY2015). (2) PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance, was classified in Category 2 for this hazard class (GHS classification in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
4 | Respiratory sensitization | Category 1 |
Danger |
H334 | P304+P340 P342+P311 P261 P284 P501 |
[Rationale for the Classification] It was classified in Category 1 by applying concentration limits in JIS Z7252:2019 from (1), (2). [Evidence Data] (1) 4,4'-MDI, >= 25% of which is contained in this substance, was classified in Category 1 for this hazard class (GHS classification in FY2015). (2) PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance, was classified in Category 1 for this hazard class (GHS classification in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
4 | Skin sensitization | Category 1 |
Warning |
H317 | P302+P352 P333+P313 P362+P364 P261 P272 P280 P321 P501 |
[Rationale for the Classification] It was classified in Category 1 by applying concentration limits in JIS Z7252:2019 from (1), (2). [Evidence Data] (1) 4,4'-MDI, >= 25% of which is contained in this substance, was classified in Category 1 for this hazard class (GHS classification in FY2015). (2) PMDI (structurally close to higher oligomers), >= 10% of which is contained in this substance, was classified in Category 1 for this hazard class (GHS classification in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
5 | Germ cell mutagenicity | Classification not possible |
- |
- | - | [Rationale for the Classification] Classification not possible due to lack of data. [Evidence Data] (1) 4,4'-MDI which is an ingredient contained in this substance at 25% or higher was classified as "Classification not possible" for this hazard class in the GHS classification (GHS Classification Results in FY2015). (2) PMDI having a structure similar to that of higher oligomers which is an ingredient contained in this substance at 10% or higher was classified as "Classification not possible" for this hazard class in the GHS classification (GHS Classification Results in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
6 | Carcinogenicity | Category 2 |
Warning |
H351 | P308+P313 P201 P202 P280 P405 P501 |
[Rationale for the Classification] Based on (1) and (2), it was classified in Category 2, applying the concentration limits of JIS Z7252:2019. [Evidence Data] (1) 4,4'-MDI which is an ingredient contained in this substance at 25% or higher was classified as "Classification not possible" for this hazard class in the GHS classification (GHS Classification Results in FY2015). (2) PMDI having a structure similar to that of higher oligomers which is an ingredient contained in this substance at 10% or higher was classified in Category 2 for this hazard class in the GHS classification (GHS Classification Results in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
7 | Reproductive toxicity | Classification not possible |
- |
- | - | [Rationale for the Classification] Classification not possible due to lack of data. [Evidence Data] (1) 4,4'-MDI which is an ingredient contained in this substance at 25% or higher was classified as "Classification not possible" for this hazard class in the GHS classification (GHS Classification Results in FY2015). (2) PMDI having a structure similar to that of higher oligomers which is an ingredient contained in this substance at 10% or higher was classified as "Classification not possible" for this hazard class in the GHS classification (GHS Classification Results in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
8 | Specific target organ toxicity - Single exposure | Category 1 (respiratory organs) |
Danger |
H370 | P308+P311 P260 P264 P270 P321 P405 P501 |
[Rationale for the Classification] Based on (1) and (2), it was classified in Category 1 (respiratory organs), applying the concentration limits of JIS Z7252:2019. [Evidence Data] (1) 4,4'-MDI which is an ingredient contained in this substance at 25% or higher was classified in Category 1 (respiratory organs) for this hazard class in the GHS classification (GHS Classification Results in FY2015). (2) PMDI having a structure similar to that of higher oligomers which is an ingredient contained in this substance at 10% or higher was classified in Category 1 (respiratory organs) for this hazard class in the GHS classification (GHS Classification Results in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
9 | Specific target organ toxicity - Repeated exposure | Category 1 (respiratory organs) |
Danger |
H372 | P260 P264 P270 P314 P501 |
[Rationale for the Classification] Based on (1) and (2), it was classified in Category 1 (respiratory organs), applying the concentration limits of JIS Z7252:2019. [Evidence Data] (1) 4,4'-MDI which is an ingredient contained in this substance at 25% or higher was classified in Category 1 (respiratory organs) for this hazard class in the GHS classification (GHS Classification Results in FY2015). (2) PMDI having a structure similar to that of higher oligomers which is an ingredient contained in this substance at 10% or higher was classified in Category 1 (respiratory organs) for this hazard class in the GHS classification (GHS Classification Results in FY2020). |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
10 | Aspiration hazard | Classification not possible |
- |
- | - | [Rationale for the Classification] Classification not possible due to lack of data. |
FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment Short term (Acute) | Classification not possible |
- |
- | - | No data available. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
11 | Hazardous to the aquatic environment Long term (Chronic) | Classification not possible |
- |
- | - | No data available. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
12 | Hazardous to the ozone layer | Classification not possible |
- |
- | - | This substance is not listed in the Annexes to the Montreal Protocol. | FY2020 | GHS Classification Guidance for the Japanese Government (FY2019 revised edition (Ver. 2.0)) |
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