Item | Information |
---|---|
CAS RN | |
Chemical Name | Powder cake (1) [composition: nitroglycerin/nitrocellulose/water = 60/15/25] |
Substance ID | m-nite-nocas-0023_v1 |
Download of Excel format | Excel file |
Item | Information |
---|---|
Guidance used for the classification (External link) | To Guidance List |
UN GHS document (External link) | To UN GHS document |
FAQ(GHS classification results by the Japanese Government) | To FAQ |
List of Information Sources (Excel file) | List of Information Sources |
List of Definitions/Abbreviations | Definitions/Abbreviations |
Sample Label by MHLW (External link) | MHLW Website (in Japanese Only) |
Sample SDS by MHLW (External link) | MHLW Website (in Japanese Only) |
OECD/eChemPortal (External link) | To OECD/eChemPortal (External link) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Explosives | Division 1.3 |
Danger |
H203 | P370+P372+P380+P373 P210 P230 P234 P240 P250 P280 P401 P501 |
It is rated as UN0159 and Division 1.3. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
2 | Flammable gases | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
3 | Aerosols | Not classified (Not applicable) |
- |
- | - | Not aerosol products. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
4 | Oxidizing gases | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
5 | Gases under pressure | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
6 | Flammable liquids | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
7 | Flammable solids | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
8 | Self-reactive substances and mixtures | Not classified (Not applicable) |
- |
- | - | Since the substance is classified as an explosive, classification as a self-reactive substance is not applicable. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
9 | Pyrophoric liquids | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
10 | Pyrophoric solids | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
11 | Self-heating substances and mixtures | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
12 | Substances and mixtures which, in contact with water, emit flammable gases | Not classified (Not applicable) |
- |
- | - | The chemical structure of the substance does not contain metals or metalloids. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
13 | Oxidizing liquids | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
14 | Oxidizing solids | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
15 | Organic peroxides | Not classified (Not applicable) |
- |
- | - | Containing no bivalent -O-O- structure in the molecule | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
16 | Corrosive to metals | Classification not possible |
- |
- | - | No data available. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
17 | Desensitized explosives | - |
- |
- | - | - | - | - |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
1 | Acute toxicity (Oral) | Category 3 |
Danger |
H301 | P301+P310 P264 P270 P321 P330 P405 P501 |
The LD50 for rats given to nitroglycerin is 100 mg/kg (calculated by the Japanese Government's agency which conducted classifications) and that for rats given nitrocellulose is > 5000 mg/kg (Japanese Government's classification). Based on the nitroglycerin LD50 value, the LD50 for this compound was computed to be 167 mg/kg and was classified into Category 3 (we ignored the toxic value for nitrocellulose in calculations). | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Dermal) | Classification not possible |
- |
- | - | Classification of nitroglycerin is not possible due to lack of test results (Japanese Government's classification), and nitrocellulose was classified into the "Not classified" category based on its LD50 value of > 29200. Giving priority to the classification of nitroglycerin, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Inhalation: Gases) | Not classified (Not applicable) |
- |
- | - | Solid | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Inhalation: Vapours) | Classification not possible |
- |
- | - | Since both nitroglycerin and nitrocellulose are classified into the "Classification not possible" category, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
1 | Acute toxicity (Inhalation: Dusts and mists) | Classification not possible |
- |
- | - | Since both nitroglycerin and nitrocellulose are classified into the "Classification not possible" category, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
2 | Skin corrosion/irritation | Classification not possible |
- |
- | - | Since both nitroglycerin and nitrocellulose are classified into the "Classification not possible" category, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
3 | Serious eye damage/eye irritation | Category 2A |
Warning |
H319 | P305+P351+P338 P337+P313 P264 P280 |
Because nitroglycerin is classified into Category 2A to 2B, this compound was also classified into Category 2A to 2B assuming the same cutoff values. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
4 | Respiratory sensitization | Classification not possible |
- |
- | - | Since both nitroglycerin and nitrocellulose have been classified into the "Classification not possible" category, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
4 | Skin sensitization | Category 1 |
Warning |
H317 | P302+P352 P333+P313 P362+P364 P261 P272 P280 P321 P501 |
Because nitroglycerin is classified into Category 1, this compound was also classified into Category 1 assuming the same cutoff values. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
5 | Germ cell mutagenicity | Classification not possible |
- |
- | - | Because nitroglycerin is classified into the "Classification not possible" category, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
6 | Carcinogenicity | Classification not possible |
- |
- | - | Since both nitroglycerin and nitrocellulose are classified into the "Classification not possible" category, this compound was classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
7 | Reproductive toxicity | Category 2 |
Warning |
H361 | P308+P313 P201 P202 P280 P405 P501 |
Because nitroglycerin is classified into Category 2, this compound was also classified into Category 2 assuming the same cutoff values. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
8 | Specific target organ toxicity - Single exposure | Category 1 (cardiovascular system, blood) |
Danger |
H370 | P308+P311 P260 P264 P270 P321 P405 P501 |
Because nitroglycerin is classified into Category 1 for its toxicity to the cardiovascular system and blood, this compound was also classified into Category 1 (cardiovascular system and blood) assuming the same cutoff values. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
9 | Specific target organ toxicity - Repeated exposure | Category 1 (cardiovascular system) |
Danger |
H372 | P260 P264 P270 P314 P501 |
Because nitroglycerin is classified into Category 1 for its toxicity to the cardiovascular system, this compound was also classified into Category 1 (cardiovascular system) assuming the same cutoff values. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
10 | Aspiration hazard | Classification not possible |
- |
- | - | Since both nitroglycerin and nitrocellulose are classified into the "Classification not possible" category, this compoundwas classified into the "Classification not possible" category. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
Hazard class | Classification | Pictogram Signal word |
Hazard statement (code) |
Precautionary statement (code) |
Rationale for the classification | Classification year (FY) | GHS Classification Guidance for the Japanese Government | |
---|---|---|---|---|---|---|---|---|
11 | Hazardous to the aquatic environment Short term (Acute) | Category 2 |
- |
H401 | P273 P501 |
Regarding nitroglycerin (CAS: 55-63-0), its 96-hour LC50 for fish (bluegulls) is 1.38 mg/L (Hazard Data Book for Chemical Substance (CERI), 2002) and it is classified into Category 2. Regarding nitrocellulose (CAS: 9004-70-0), its 96-hour EC50 for algae (Selenastrum) is 579000 microg/L (AQUIRE, 2003) and it is classified into the "Not classified" category. As this compound is composed of 60% nitroglycerin, 15% nitrocellulose, and 25% water, it was classified into Category 2. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
11 | Hazardous to the aquatic environment Long term (Chronic) | Category 2 |
- |
H411 | P273 P391 P501 |
Regarding nitroglycerin (CAS: 55-63-0), its classification for acute toxicity is Category 2, its potential for bioaccumulation is presumably low (log Kow = 1.62 (PHYSPROP Database, 2005), and it is estimated not to be rapidly degradable (BIOWIN). Based on this information, nitroglycerin was classified into Category 2. Regarding nitrocellulose (CAS: 9004-70-0), it is water soluble (water solubility = 1.00*10^6 mg/L (PHYSPROP Database, 2005) and its acute toxicity is low. Based on this information, nitrocellulose was classified into the "Not classified" category. As this compound is composed of 60% nitroglycerin, 15% nitrocellulose, and 25% water, it was classified into Category 2. | FY2007 | GHS Classification Manual (10 Feb, 2006)/Technical Guidance Document on the GHS Classification (6 Dec, 2005) |
12 | Hazardous to the ozone layer | - |
- |
- | - | - | - | - |
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