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General Information
- General Information
  - General Information Data Description
    - CHRIP_ID C004-663-91A CAS RN 75-45-6
      
      Chemical Substance Name Chloro(difluoro)methane
      
      Molecular Formula CHClF2
      
      Molecular Weight 86
      
      SMILES FC(Cl)F
      
      Structure
- Synonym
  - Synonym Data Description
    - Synonym Chlorodifluoromethane
      
      HCFC 22
      
      Methane, chlorodifluoro-
      
      Monochlorodifluoromethane
      
      R 22
- Nikkaji
  - Information of Japan Chemical Substance Dictionary (Nikkaji) Data Description
    - Nikkaji Number
      J1.455I
      Detail to J-GLOBAL

Laws and Regulations in Japan

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc. (Chemical Substances Control Law ; CSCL)

Japan CSCL: Canceled Priority Assessment Chemical Substances Data Description

Registration Number	197	Date of Cancellation	2023/03/31
MITI Number	2-93	Date of designation as a priority assessment chemical substance	2016/04/01
Chemical Substance Name	Chlorodifluoromethane
Remarks	-
Remarks of Cancellation	-
Details	to J-CHECK

Japan CSCL: Existing Chemical Substances Data Description Definition of the terms of Section 6 [PDF] Definition of the terms of Section 7 [PDF] Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]

MITI Number	2-93	Category	Section 2
Chemical Substance Name	Chlorodifluoromethane
Remarks	-
Details	to J-CHECK
Remarks to Existing Chemical Substances of Industrial Safety and Health Act	Chemicals have been notified in accordance with the provisions of Chemical Substances Control Law by June 29, 1979
Details to Existing Chemical Substances of Industrial Safety and Health Act	to MHLW site (in Japanese)

Japan METI: Biodegradation and Bioconcentration Results Data Description

Chemical Substance Name	chlorodifluoromethane
Judgement of Biodegradation	Not readily biodegradable	Judgement of Bioconcentration	Low bioconcentration
Test result of Bioconcentration	-	Test result of Partition Coefficient	-
Details	to J-CHECK

Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management Thereof(PRTR-SDS Law)

Japan: PRTR-SDS Law (until March 2023) Data Description Outline PRTR Law (METI site) Analysis of PRTR data

Classification	I	Cabinet Order Number	1-104
Cabinet Order Name	Chlorodifluoromethane (synonym: HCFC-22)
Remarks	-
Basis of selection	Hazard Data (in Japanese)
Link	Releases Map (in Japanese) Atmospheric concentration Map (in Japanese)

Japan: PRTR-SDS Law (from April 2023) Data Description Outline PRTR Law (METI site)

JPSN(Japan PRTR-SDS Number)	104	Classification	I	Cabinet Order Number	1-130
Cabinet Order Name	Chlorodifluoromethane (synonym: HCFC-22)
Remarks	-
Basis of selection	Hazard Data (in Japanese)
Link	- -

Industrial Safety and Health Act (ISHA)

Japan ISHA: Chemical Substances Requiring Labeling and Delivery of Documents, etc. Data Description GHS compatible model label creation method (MH LW site : in Japanese) Risk assessment implementation support tool (MHLW site : in Japanese)

Cabinet Order Number	Attached table 9-149 of Cabinet order
Cabinet Order Name	Chlorodifluoromethane(otherwise known as HCFC-22)
Range of Application for Label (weight%)	>=1
Range of Application for SDS (weight%)	>=0.1

Act on the Protection of the Ozone Layer through the Control and Other Measures on Specified Substances and Other Substances

Japan Act on the Protection of the Ozone Layer through the Control of Specified Substances and Other Measures Data Description Protect the ozone layer Prevent global warming [PDF] To UNEP site

Category	Specified Substances	Cabinet Order Number (Type of Substances)	Attached Table 1-6-2 (C-I)
Cabinet Order Name	Chlorodifluoromethane (HCFC-22)
Potential value	0.055 (Ozone-Depleting Potential)

Air Pollution Control Act

Japan Air Pollution Control Law Data Description Air & Transportation (MOE site)

Classification	Substances Excluded from Volatile Organic Compounds (VOC)	Cabinet Order Number	Article 2-2-2 of Cabinet order
Cabinet Order Name	chlorodifluoromethane (HCFC-22)
Remarks	Exempted Substances Specified by Cabinet Order under Article 2, Paragraph (4) of the Act

High Pressure Gas Safety Act

High Pressure Gas Safety Act Data Description

Classification	Class 1 Gas	Applicable provisions of Laws and Regulations, etc.	Cabinet Order 2(3)(iv)
Name in Laws and Regulations, etc.	Fluorocarbons (limited to those conforming to the flammability standards specified by the Ordinance of the Ministry of Economy, Trade and Industry as having flame retardant properties)

High Pressure Gas Safety Act : Regulation on Safety of General High Pressure Gas Data Description
- Classification Inactive Gas Applicable provisions of Laws and Regulations, etc.
  Ministerial Order 2(1)(iv)
  
  Name in Laws and Regulations, etc. Fluorocarbons(except flammable gas)

High Pressure Gas Safety Act : Regulation on Safety of Refrigeration Data Description

Classification	Flammable gas	Applicable provisions of Laws and Regulations, etc.	Ministerial Order 2(1)(i)
Name in Laws and Regulations, etc.	Any Other Gas Which Falls Under Any Of The Following (A) Or (B) (Excluding Liquefied Fluoroolefin 1234Yf And Liquefied Fluoroolefin 1234Ze):(A)Gas Of Which The Minimum Explosive Limit (Meaning An Explosive Limit In The Case Of Mixture With Air; The Same A
Remarks	R-406A, R-411A, R-411B, R-412A, R-415A, R-415B, R-418A

Classification	Inactive gas	Applicable provisions of Laws and Regulations, etc.	Ministerial Order 2(1)(iii)
Name in Laws and Regulations, etc.	Fluorocarbons (Excluding Flammable Gases)
Remarks	R-22, R-401A, R-401B, R-401C, R-402A, R-402B, R-403A, R-403B, R-408A, R-409A, R-409B, R-414A, R-414B, R-501, R-502, R-509A

Classification	Refrigerant gas	Applicable provisions of Laws and Regulations, etc.	Ministerial Order 5(1)(iii)
Name in Laws and Regulations, etc.	Liquefied Fluorocarbon 22 (HFC-22)
Remarks	R-22

Classification	Refrigerant gas	Applicable provisions of Laws and Regulations, etc.	Ministerial Order 5(1)(iv)
Name in Laws and Regulations, etc.	Liquefied Fluorocarbon 502 (HFC-502)
Remarks	R-502

Classification	Refrigerant gas	Applicable provisions of Laws and Regulations, etc.	Ministerial Order 5(1)(iv)
Name in Laws and Regulations, etc.	Other Gases
Remarks	R-401A, R-401B, R-401C, R-402A, R-402B, R-403A, R-403B, R-406A, R-408A, R-409A, R-409B, R-411A, R-411B, R-412A, R-414A, R-414B, R-415A, R-415B, R-418A, R-501, R-509A

Classification	Refrigerant gas	Applicable provisions of Laws and Regulations, etc.	Ministerial Order 5(1)(iv)
Name in Laws and Regulations, etc.	Liquefied Fluorocarbon 22 (HFC-22)
Remarks	R-22

Laws and Regulations in Other countries

Recommendations on the transport of dangerous goods

Dangerous Goods List (UN Number and Hazard class) Data Description

UN Number	1018	Class or Division	2.2
Name and Description	CHLORODIFLUOROMETHANE (REFRIGERANT GAS R 22)

UN Number	1973	Class or Division	2.2
Name and Description	CHLORODIFLUOROMETHANE AND CHLOROPENTAFLUOROETHANE MIXTURE with fixed boiling point, with approximately 49% chlorodifluoromethane (REFRIGERANT GAS R 502)

International Convention on the Commodity Description and Coding Systems (HS Convention)

HS Code: Section VI “Products of the Chemical or Allied Industries" Data Description

Chapter	29	Chapter name	Organic chemicals
Heading	2903	Substance name (Heading)	Halogenated derivatives of hydrocarbons
HS Code	2903.71	Substance Name	Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens : Chlorodifluoromethane

Association of South-East Asian Nations(ASEAN)
- The ASEAN-Japan Chemical Safety Database (AJCSD).: Laws and Regulations Data Description
  - Detail to AJCSD
- The ASEAN-Japan Chemical Safety Database (AJCSD).: GHS-Related Information Data Description
  - Detail to AJCSD

European Union (EU)
- EC Inventory Data Description
  - EC Number
    200-871-9
    
    EC Name Chlorodifluoromethane
    
    Description -
    
    Substance Infocard Infocard
    
    ECHA Name -

US: Toxic Substances Control Act (TSCA)
- TSCA Inventory Data Description
  - TSCA Chemical Substance Name Methane, chlorodifluoro-
    
    DEF -
    
    UVCB -
    
    FLAG -
    
    ACTIVITY ACTIVE

China
- China: Catalog of Hazardous Chemicals 2015 Data Description
  - Number
    2552
    
    Name Monochlorodifluoromethane
    
    Other Name R22;Difluoromonochloromethane;Chlorodifluoromethane
    
    Remarks -

Korea

Korea: ARECs (K-REACH); Existing Chemical Substances Data Description

KE Number	KE-25490
Category	Existing Chemical Substances (Domestically distributed commercial purpose before February 2, 1991.)
Chemical Substance Name	Monochlorodifluoromethane ; Freon 22
Remarks	In the case of being hydrated, the resulting hydrate is also applicable.

Taiwan
- Taiwan: TCCSCA/OSHA; Existing Chemical Substances Data Description
  - English Name chlorodifluoromethane
    
    Chinese Name -

Chemical Hazard and Risk Information
- GHS Classification Results
  - NITE Japan-GHS Data Description
    - Edition version_1
      
      Chemical Substance Name Chlorodifluoromethane
      
      Classification Result To the resut webpage To the Excel flie
  - GHS Classification Results by the Japanese Government Data Description GHS Information
    - Year of implementation /renewal 2006 ID 114_H18_new
      
      Chemical Substance Name Methane, chlorodifluoro-
      
      Classification Result To the resut webpage To the Excel flie
      
      Year of implementation /renewal 2014 ID H26-B-038 / R-016
      
      Chemical Substance Name Chlorodifluoromethane
      
      Classification Result To the resut webpage To the Excel flie
- MHLW:GHS Aligned Sample Label and SDS
  - GHS Aligned Sample Label and SDS Data Description Information on GHS Aligned Sample Label and SDS (Workplace Safety Site)
    - Chemical Substance Name Methane, chlorodifluoro-
      
      Sample Label to MHLW Website (in Japanese Only)
      
      Sample SDS to MHLW Website (in Japanese Only)
- AIST: Relational Information System for Chemical Accidents Database(RISCAD)
  - Relational Information System for Chemical Accidents Database(RISCAD) Data Description RISCAD (in Japanese)
    - Material ID 277
      
      Name chlorodifluoromethane
      
      Material Information to RISCAD
      
      Accident Information to RISCAD
- Hazard and Risk Assessment Reports etc. in Japan
  - ISHA: Examples of Occupational Accidents Caused by Chemical Substances Data Description
    - Name Fron
      
      Examples of Occupational Accidents to MHLW site (in Japanese)
      
      Name Chlorodifluoromethane
      
      Examples of Occupational Accidents to MHLW site (in Japanese)
  - Hazard Data Sheet for Chemical Substances Data Description
    - Book Number
      96-24
      Date of publication/ renewal 1997/07
      
      Assessed Chemical Substance Name Chlorodifluoromethane
      
      Details Hazard Data Sheet (in Japanese)
  - CSCL: The Japan HPV Challenge Program Data Description
    - Chemical Substance Name chlorodifluoromethane
      
      Details to J-CHECK
- Hazard and Risk Assessment Reports etc. in Other Countries
  - OECD: High Production Volume (HPV) Chemicals Data Description
    - Chemical Name Methane, chlorodifluoro-
      
      Details to OECD Existing Chemicals Database
  - International Chemical Safety Cards (ICSC) Data Description
    - ICSC Number
      49
      
      ICSC Title Chlorodifluoromethane
      
      Details to ILO site
  - Environmental Health Criteria (EHC) Data Description
    - EHC Number
      126
      
      EHC Title Partially halogenated chlorofluorocarbons (methane derivatives)
      
      Details to IPCS site
  - US EPA: Integrated Risk Information System (IRIS) Data Description
    - Chemical Substance Name Chlorodifluoromethane
      
      Details to EPA site Last Revision 1993/11/01
  - EU: Risk Assessment Reports (RAR) Data Description
    - EC Number
      200-871-9
      Date 2008/11/21
      
      Report Title Chlorodifluoromethane
      
      Details to ECHA site
- Japan Society for Occupational Health (JSOH) Recommendation of Occupational Exposure Limits
  - JSOH: Occupational Exposure Limits Data Description
    - Substance Name Chlorodifluoromethane
      
      Occupational Exposure Limit (ppm) 1000
      
      Occupational Exposure Limit (mg/m3) 3500
      
      Details Documentation in Japanese
      
      Year of proposal 1987
      
      Remarks -
  - JSOH: Reproductive Toxicants Data Description
    - Substance Name Chlorodifluoromethane
      
      Reproductive toxicant classification 2
      
      Details Summary
      
      Year of proposal 2014
      
      Remarks -
- Carcinogenicity Assessment
  - IARC: Carcinogenicity Assessment Data Description to IARC site
    - Volume 41, Sup 7, 71 Volume publication year 1999
      
      Agent Name Chlorodifluoromethane
      
      Group 3
      
      Details Vol.41 Sup 7 Vol.71 - -

Test Data and Reports

Japan METI: Biodegradation and Bioconcentration Results Data Description

Chemical Substance Name	chlorodifluoromethane
Judgement of Biodegradation	Not readily biodegradable	Judgement of Bioconcentration	Low bioconcentration
Test result of Bioconcentration	-	Test result of Partition Coefficient	-
Details	to J-CHECK

ISHA: Mutagenicity Test Results for Chemical Substances Data Description to MHLW site (in Japanese)
- Chemical Name Chlorodifluoromethane(Gas)
  
  Bacterial Test Positive
  
  CHL/IU Test Negative

CHRIP_ID	C004-663-91A	CAS RN	75-45-6
Chemical Substance Name	Chloro(difluoro)methane
Molecular Formula	CHClF2
Molecular Weight	86
SMILES	FC(Cl)F
Structure

Synonym	Chlorodifluoromethane
	HCFC 22
	Methane, chlorodifluoro-
	Monochlorodifluoromethane
	R 22

EC Number	200-871-9
EC Name	Chlorodifluoromethane
Description	-
Substance Infocard	Infocard
ECHA Name	-

TSCA Chemical Substance Name	Methane, chlorodifluoro-
DEF	-
UVCB	-
FLAG	-
ACTIVITY	ACTIVE

Number	2552
Name	Monochlorodifluoromethane
Other Name	R22;Difluoromonochloromethane;Chlorodifluoromethane
Remarks	-

Edition	version_1
Chemical Substance Name	Chlorodifluoromethane
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2006	ID	114_H18_new
Chemical Substance Name	Methane, chlorodifluoro-
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2014	ID	H26-B-038 / R-016
Chemical Substance Name	Chlorodifluoromethane
Classification Result	To the resut webpage To the Excel flie

Chemical Substance Name	Methane, chlorodifluoro-
Sample Label	to MHLW Website (in Japanese Only)
Sample SDS	to MHLW Website (in Japanese Only)

Material ID	277
Name	chlorodifluoromethane
Material Information	to RISCAD
Accident Information	to RISCAD

Name	Fron
Examples of Occupational Accidents	to MHLW site (in Japanese)

Book Number	96-24	Date of publication/ renewal	1997/07
Assessed Chemical Substance Name	Chlorodifluoromethane
Details	Hazard Data Sheet (in Japanese)

Chemical Name	Methane, chlorodifluoro-
Details	to OECD Existing Chemicals Database

ICSC Number	49
ICSC Title	Chlorodifluoromethane
Details	to ILO site

EHC Number	126
EHC Title	Partially halogenated chlorofluorocarbons (methane derivatives)
Details	to IPCS site

EC Number	200-871-9	Date	2008/11/21
Report Title	Chlorodifluoromethane
Details	to ECHA site

Substance Name	Chlorodifluoromethane
Occupational Exposure Limit (ppm)	1000
Occupational Exposure Limit (mg/m3)	3500
Details	Documentation in Japanese
Year of proposal	1987
Remarks	-

Substance Name	Chlorodifluoromethane
Reproductive toxicant classification	2
Details	Summary
Year of proposal	2014
Remarks	-

Volume	41, Sup 7, 71	Volume publication year	1999
Agent Name	Chlorodifluoromethane
Group	3
Details	Vol.41 Sup 7 Vol.71 - -

Chemical Name	Chlorodifluoromethane(Gas)
Bacterial Test	Positive
CHL/IU Test	Negative