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General Information
- General Information
  - General Information Data Description
    - CHRIP_ID C004-702-40A CAS RN 68-12-2
      
      Chemical Substance Name N,N-Dimethylformamide
      
      Molecular Formula C3H7NO
      
      Molecular Weight 73
      
      SMILES O=CN(C)C
      
      Structure
- Synonym
  - Synonym Data Description
    - Synonym Dimethylformamide
      
      DMF
      
      DMFA
      
      Formamide, N,N-dimethyl-
      
      Formyldimethylamine
      
      N-formyldimethylamine
- Nikkaji
  - Information of Japan Chemical Substance Dictionary (Nikkaji) Data Description
    - Nikkaji Number
      J1.923B
      Detail to J-GLOBAL

Laws and Regulations in Japan

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc. (Chemical Substances Control Law ; CSCL)

Japan CSCL: Priority Assessment Chemical Substances Data Description Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]
- Registration Number
  27
  Date of Designation 2011/04/01
  
  MITI Number
  2-680
  
  Chemical Substance Name N,N-Dimethylformamide
  
  Reason for Inclusion Human Health
  
  Remarks -
  
  Details to J-CHECK

Japan CSCL: Existing Chemical Substances Data Description Definition of the terms of Section 6 [PDF] Definition of the terms of Section 7 [PDF] Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]

MITI Number	2-680	Category	Section 2
Chemical Substance Name	N,N-Dimethylformamide
Remarks	-
Details	to J-CHECK
Remarks to Existing Chemical Substances of Industrial Safety and Health Act	Chemicals have been notified in accordance with the provisions of Chemical Substances Control Law by June 29, 1979
Details to Existing Chemical Substances of Industrial Safety and Health Act	to MHLW site (in Japanese)

Japan CSCL: Type II Monitoring Chemical Substances (before amendment) Data Description Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]
- Registration Number
  387
  Date of Designation in the Official Gazette 2000/09/22
  
  MITI Number
  2-680
  
  Chemical Substance Name N,N-Dimethylformamide
  
  Remarks -
  
  Details to J-CHECK

Japan METI: Biodegradation and Bioconcentration Results Data Description

Chemical Substance Name	dimethylformamide
Judgement of Biodegradation	Not readily biodegradable	Judgement of Bioconcentration	Low bioconcentration
Test result of Bioconcentration	-	Test result of Partition Coefficient	-
Details	to J-CHECK

Japan MOE: Results of Eco-toxicity tests of chemicals Data Description
- Chemical Substance Name Dimethylformamide
  
  Details to J-CHECK

Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management Thereof(PRTR-SDS Law)

Japan: PRTR-SDS Law (until March 2023) Data Description Outline PRTR Law (METI site) Analysis of PRTR data

Classification	I	Cabinet Order Number	1-232
Cabinet Order Name	N,N-Dimethylformamide
Remarks	-
Basis of selection	Hazard Data (in Japanese)
Link	Releases Map (in Japanese) Atmospheric concentration Map (in Japanese)

Japan: PRTR-SDS Law (from April 2023) Data Description Outline PRTR Law (METI site)

JPSN(Japan PRTR-SDS Number)	232	Classification	I	Cabinet Order Number	1-264
Cabinet Order Name	N,N-Dimethylformamide
Remarks	-
Basis of selection	Hazard Data (in Japanese)
Link	- -

Industrial Safety and Health Act (ISHA)

Japan ISHA: Chemical Substances Requiring Labeling and Delivery of Documents, etc. Data Description GHS compatible model label creation method (MH LW site : in Japanese) Risk assessment implementation support tool (MHLW site : in Japanese)

Cabinet Order Number	Attached table 9-299 of Cabinet order
Cabinet Order Name	N,N-Dimethylformamide
Range of Application for Label (weight%)	>=0.3
Range of Application for SDS (weight%)	>=0.1

Cabinet Order Number	Attached table 9-298 of Cabinet order: To be enforced from April 1, 2024
Cabinet Order Name	N,N-Dimethylformamide
Range of Application for Label (weight%)	>=0.3
Range of Application for SDS (weight%)	>=0.1

Japan ISHA: Carcinogenic Substances (Ordinance on Industrial Safety and Health) (subject to 30-year storage of work records, etc.) Data Description Lists of Target Substances (MHLW site : in Japanese)

GHS Classification Substance Name	N,N-Dimethylformamide
Carcinogenicity in GHS classification	Category 1B	Range of Application (weight%)	>=0.1
Implementation	2023/4/1
Details	to the GHS Classification

Japan ISHA: Chemical substances that cause skin disorders, etc. and other chemical substances that must be handled with impermeable protective equipment etc. based on special chemical regulations. Data Description Target substances list(MHLW site: in japanese)
- Substance Name N,N-Dimethylformamide
  
  Classification of Target Substances Skin Absorbing Hazardous Substances Cutoff value(weight %) 0.1
  
  Implementation 2024/4/1
  
  Details to the GHS Classification

Japan ISHA: Organic Solvents Data Description Proper use of organic solvent (MHLW site : in Japanese)
- Category Second-class organic solvents, etc. Cabinet Order Number
  30
  
  Cabinet Order Name N,N-Dimethylformamide
  
  The above information have been provided by the Ministry of Health, Labour and Welfare

Japan ISHA: Administrative Control Levels of Working Environment Evaluation Standards Data Description Working Environment Measurement (MHLW site : in Japanese)
- Registration Number
  59
  
  Kinds of substances N,N-Dimethylformamide
  
  Control Level 10ppm
  
  The above information have been provided by the Ministry of Health, Labour and Welfare

Japan ISHA: Guidelines for Carcinogenic Substances Data Description
- Name N,N-Dimethylformamide
  
  Details to MHLW site (in Japanese)

Air Pollution Control Act

Japan Air Pollution Control Law Data Description Air & Transportation (MOE site)

Classification	Volatile Organic Compounds (VOC)	Cabinet Order Number	Article 2-4 of Act
Cabinet Order Name	Any organic compound (excluding substances specified by a Cabinet Order as not being sources from which suspended particulate matter or oxidants are generated) that is in a gaseous state at the time of its emission or dispersal into the atmosphere.
VOC Emission Inventory Substance Code	71-03-02
VOC Emission Inventory Substance Name	N,N-Dimethylformamide

Classification	Substances that may be classified as Hazardous Air Pollutants	Cabinet Order Number	105 of Central Environment Council 9th Report (Appendix 1)
Cabinet Order Name	N,N-Dimethylformamide

Fire Service Act

Fire Service Act : Hazardous Materials Data Description

Number of cabinet order etc.	Article 2, Paragraph 7 of the Act, Appended Table 1, Category IV (4)
Category; Property	Category IV; Inflammable Liquids
Item	Class II petroleums
Sources	Hazardous Materials Disaster Information Support System, Hazardous Materials Data Book 2nd edition, MHLW Website; Sample SDS

Laws and Regulations in Other countries

Recommendations on the transport of dangerous goods
- Dangerous Goods List (UN Number and Hazard class) Data Description
  - UN Number
    2265
    Class or Division 3
    
    Name and Description N,N-DIMETHYLFORMAMIDE
    
    UN packing group III

Association of South-East Asian Nations(ASEAN)
- The ASEAN-Japan Chemical Safety Database (AJCSD).: Laws and Regulations Data Description
  - Detail to AJCSD
- The ASEAN-Japan Chemical Safety Database (AJCSD).: GHS-Related Information Data Description
  - Detail to AJCSD

European Union (EU)
- EC Inventory Data Description
  - EC Number
    200-679-5
    
    EC Name N,N-dimethylformamide
    
    Description -
    
    Substance Infocard Infocard
    
    ECHA Name -
- REACH: Substances of Very High Concern for Authorization (SVHC) Data Description
  - EC Number 200-679-5 Status Candidate List
    
    Substance Name N,N-dimethylformamide
    
    Reason for inclusion
    Toxic for reproduction (Article 57c)
    
    Date of inclusion
    2012/12/19
    
    Details to ECHA site
- EU: CLP Harmonised Classification Data Description To ECHA site
  - Index Number 616-001-00-X EC Number 200-679-5
    
    Chemical Name N,N-dimethylformamide; dimethyl formamide
    
    Classification Repr. 1B / [Inh.]Acute Tox. 4 * / [Der.]Acute Tox. 4 * / Eye Irrit. 2

US: Toxic Substances Control Act (TSCA)
- TSCA Inventory Data Description
  - TSCA Chemical Substance Name Formamide, N,N-dimethyl-
    
    DEF -
    
    UVCB -
    
    FLAG -
    
    ACTIVITY ACTIVE

China
- China: Catalog of Hazardous Chemicals 2015 Data Description
  - Number
    460
    
    Name N,N-Dimethylmethanamide
    
    Other Name Methanoyldimethylamine
    
    Remarks -

Korea

Korea: ARECs (K-REACH) / CCA; Hazardous Substance(s), Priority Control Substances Data Description
- Number
  2014-1-694
  
  Category Toxic Substance(s)
  
  Chemical Substance Name N,N-Dimethylformamide
  
  Range of Application (%)
  >=0.1
  
  Number
  23
  
  Category Priority Control Substances
  
  Chemical Substance Name N,N-Dimethylformamide

Korea: ARECs (K-REACH); Existing Chemical Substances Data Description

KE Number	KE-11411
Category	Existing Chemical Substances (Domestically distributed commercial purpose before February 2, 1991.)
Chemical Substance Name	N,N-Dimethylformamide ; Dimethylformamide
Remarks	In the case of being hydrated, the resulting hydrate is also applicable.

Korea: ARECs (K-REACH); Others Data Description

Number	18
Category	Phase-in substance(s) subject to registration (by June 30, 2018)
Chemical Substance Name	N,N-Dimethylformamide; Dimethylformamide
Note	The registration grace period is until June 30, 2018

Taiwan

Taiwan: TCCSCA/OSHA; Existing Chemical Substances Data Description
- English Name N,N-dimethylformamide
  
  Chinese Name -

Taiwan: TCCSCA; Toxic Chemicals Data Description

Listed No./Series No.	98/01
Toxicity Classify	2
English Name	N,N-Dimethyl formamide
Chinese Name	二甲基甲醯胺
Control concentration standard (w/w%)	30
Large-scale handling standard(kg)	50

Chemical Hazard and Risk Information

GHS Classification Results

NITE Japan-GHS Data Description
- Edition version_1
  
  Chemical Substance Name N,N-Dimethylformamide
  
  Classification Result To the resut webpage To the Excel flie

GHS Classification Results by the Japanese Government Data Description GHS Information

Year of implementation /renewal	2006	ID	149_H18_new
Chemical Substance Name	N,N-Dimethylformamide
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2008	ID	20A2376
Chemical Substance Name	N,N-Dimethylformamide
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2018	ID	H30-C-044-MHLW
Chemical Substance Name	N,N-Dimethylformamide
Classification Result	To the resut webpage To the Excel flie
Remarks	The reclassification result of only some hazard classes. As for the other classes, please see the result in FY2008 and FY2006.

MHLW:GHS Aligned Sample Label and SDS
- GHS Aligned Sample Label and SDS Data Description Information on GHS Aligned Sample Label and SDS (Workplace Safety Site)
  - Chemical Substance Name N,N-Dimethylformamide
    
    Sample Label to MHLW Website (in Japanese Only)
    
    Sample SDS to MHLW Website (in Japanese Only)

AIST: Relational Information System for Chemical Accidents Database(RISCAD)
- Relational Information System for Chemical Accidents Database(RISCAD) Data Description RISCAD (in Japanese)
  - Material ID 937
    
    Name dimethyl formamide
    
    Material Information to RISCAD

Hazard and Risk Assessment Reports etc. in Japan

Chemical Substances Hazard Assessment Report / Initial Risk Assessment Report Data Description Guidance for Initial Risk Assessment ver.1 (in Japanese) Guidance for Initial Risk Assessment ver.2 (in Japanese)

Report Number	No.8
Assessed Chemical Substance Name	N,N-Dimethylformamide
Details	Hazard Assessment Report (in Japanese)	Date of publication/ renewal	2005/02
	Details Initial Risk Assessment Report (in Japanese)	Date of publication/ renewal	2005/07
	Details Summary of Initial Risk Assessment Report	Date of publication/ renewal	2010/05

ISHA: Risk Assessment Report Data Description to MHLW site (in Japanese)
- Name N,N-Dimethylformamide
  
  Initial Risk Assessment Report text/cover (in Japanese)

Hazard Data Sheet for Chemical Substances Data Description
- Book Number
  96-15
  Date of publication/ renewal 1997/07
  
  Assessed Chemical Substance Name N,N-Dimethylformamide
  
  Details Hazard Data Sheet (in Japanese)

CSCL: The Japan HPV Challenge Program Data Description
- Chemical Substance Name Dimethylformamide
  
  Details to J-CHECK

Hazard and Risk Assessment Reports etc. in Other Countries
- OECD: High Production Volume (HPV) Chemicals Data Description
  - Chemical Name Formamide, N,N-dimethyl-
    
    Details to OECD Existing Chemicals Database
- International Chemical Safety Cards (ICSC) Data Description
  - ICSC Number
    457
    
    ICSC Title N,N-Dimethylformamide
    
    Details to ILO site
- Concise International Chemical Assessment Documents (CICADs) Data Description
  - CICADs Number
    31
    
    CICADs Title Dimethylformamide, n,n- (CICADS 31, 2001)
    
    Details to IPCS site
- Environmental Health Criteria (EHC) Data Description
  - EHC Number
    114
    
    EHC Title Dimethylformamide
    
    Details to IPCS site
- US EPA: Integrated Risk Information System (IRIS) Data Description
  - Chemical Substance Name N,N-Dimethylformamide
    
    Details to EPA site Last Revision 1990/10/01
- US EPA: Acute Exposure Guideline Levels (AEGLs) Data Description
  - Chemical Name N,N-Dimethylformamide
    
    Status Final
    
    AEGL Values to EPA site
- Advisory Committee on Existing Chemicals (BUA) Reports by the German Chemical Society Data Description
  - BUA Number
    84, 193
    
    Substance Name N,N-Dimethylformamide
    
    Related information to BUA site
- Canada: Priority Substances List (PSL) Data Description
  - Type of Priory Substances List PSL2
    
    Report Title N,N-Dimethylformamide (DMF)
    
    Details to Environment Canada site

Japan Society for Occupational Health (JSOH) Recommendation of Occupational Exposure Limits

JSOH: Occupational Exposure Limits Data Description

Substance Name	N,N-Dimethylformamide (DMF)
Occupational Exposure Limit (ppm)	10
Occupational Exposure Limit (mg/m3)	30
Details	Documentation in Japanese
Year of proposal	1974
Remarks	Skin absorption

JSOH: Occupational Carcinogens Data Description
- Substance Name N,N-Dimethylformamide
  
  Carcinogenicity classification 2A
  
  Details Documentation in Japanese
  
  Year of proposal 1991, 2020
  
  Remarks -

JSOH: Reproductive Toxicants Data Description
- Substance Name N,N-Dimethylformamide (DMF)
  
  Reproductive toxicant classification 2
  
  Details Summary
  
  Year of proposal 2014
  
  Remarks -

Carcinogenicity Assessment
- IARC: Carcinogenicity Assessment Data Description to IARC site
  - Volume 47, 71, 115 Volume publication year 2018
    
    Agent Name N,N-Dimethylformamide
    
    Group 2A
    
    Details Vol.47 Vol.71 Vol.115 - -

Test Data and Reports

Japan METI: Biodegradation and Bioconcentration Results Data Description

Chemical Substance Name	dimethylformamide
Judgement of Biodegradation	Not readily biodegradable	Judgement of Bioconcentration	Low bioconcentration
Test result of Bioconcentration	-	Test result of Partition Coefficient	-
Details	to J-CHECK

Japan MOE: Results of Eco-toxicity tests of chemicals Data Description
- Chemical Substance Name Dimethylformamide
  
  Details to J-CHECK

ISHA: Carcinogenicity Test Results for Chemical Substances Data Description to MHLW site (in Japanese)
- Chemical Name N,N-Dimethylformamide
  
  Summary Inhalation test results (in Japanese)

ISHA: Mutagenicity Test Results for Chemical Substances Data Description to MHLW site (in Japanese)
- Chemical Name N,N-Dimethylformamide(Gas)
  
  Bacterial Test Negative
  
  CHL/IU Test -

CHRIP_ID	C004-702-40A	CAS RN	68-12-2
Chemical Substance Name	N,N-Dimethylformamide
Molecular Formula	C3H7NO
Molecular Weight	73
SMILES	O=CN(C)C
Structure

Synonym	Dimethylformamide
	DMF
	DMFA
	Formamide, N,N-dimethyl-
	Formyldimethylamine
	N-formyldimethylamine

Registration Number	27	Date of Designation	2011/04/01
MITI Number	2-680
Chemical Substance Name	N,N-Dimethylformamide
Reason for Inclusion	Human Health
Remarks	-
Details	to J-CHECK

Registration Number	387	Date of Designation in the Official Gazette	2000/09/22
MITI Number	2-680
Chemical Substance Name	N,N-Dimethylformamide
Remarks	-
Details	to J-CHECK

Substance Name	N,N-Dimethylformamide
Classification of Target Substances	Skin Absorbing Hazardous Substances	Cutoff value(weight %)	0.1
Implementation	2024/4/1
Details	to the GHS Classification

Category	Second-class organic solvents, etc.	Cabinet Order Number	30
Cabinet Order Name	N,N-Dimethylformamide

Registration Number	59
Kinds of substances	N,N-Dimethylformamide
Control Level	10ppm

UN Number	2265	Class or Division	3
Name and Description	N,N-DIMETHYLFORMAMIDE
UN packing group	III

EC Number	200-679-5
EC Name	N,N-dimethylformamide
Description	-
Substance Infocard	Infocard
ECHA Name	-

EC Number	200-679-5	Status	Candidate List
Substance Name	N,N-dimethylformamide
Reason for inclusion	Toxic for reproduction (Article 57c)
Date of inclusion	2012/12/19
Details	to ECHA site

Index Number	616-001-00-X	EC Number	200-679-5
Chemical Name	N,N-dimethylformamide; dimethyl formamide
Classification	Repr. 1B / [Inh.]Acute Tox. 4 * / [Der.]Acute Tox. 4 * / Eye Irrit. 2

TSCA Chemical Substance Name	Formamide, N,N-dimethyl-
DEF	-
UVCB	-
FLAG	-
ACTIVITY	ACTIVE

Number	460
Name	N,N-Dimethylmethanamide
Other Name	Methanoyldimethylamine
Remarks	-

Number	2014-1-694
Category	Toxic Substance(s)
Chemical Substance Name	N,N-Dimethylformamide
Range of Application (%)	>=0.1

Number	23
Category	Priority Control Substances
Chemical Substance Name	N,N-Dimethylformamide

Edition	version_1
Chemical Substance Name	N,N-Dimethylformamide
Classification Result	To the resut webpage To the Excel flie

Chemical Substance Name	N,N-Dimethylformamide
Sample Label	to MHLW Website (in Japanese Only)
Sample SDS	to MHLW Website (in Japanese Only)

Material ID	937
Name	dimethyl formamide
Material Information	to RISCAD

Name	N,N-Dimethylformamide
Initial Risk Assessment Report	text/cover (in Japanese)

Book Number	96-15	Date of publication/ renewal	1997/07
Assessed Chemical Substance Name	N,N-Dimethylformamide
Details	Hazard Data Sheet (in Japanese)

ICSC Number	457
ICSC Title	N,N-Dimethylformamide
Details	to ILO site

CICADs Number	31
CICADs Title	Dimethylformamide, n,n- (CICADS 31, 2001)
Details	to IPCS site

BUA Number	84, 193
Substance Name	N,N-Dimethylformamide
Related information	to BUA site

Type of Priory Substances List	PSL2
Report Title	N,N-Dimethylformamide (DMF)
Details	to Environment Canada site

Substance Name	N,N-Dimethylformamide
Carcinogenicity classification	2A
Details	Documentation in Japanese
Year of proposal	1991, 2020
Remarks	-

Substance Name	N,N-Dimethylformamide (DMF)
Reproductive toxicant classification	2
Details	Summary
Year of proposal	2014
Remarks	-

Volume	47, 71, 115	Volume publication year	2018
Agent Name	N,N-Dimethylformamide
Group	2A
Details	Vol.47 Vol.71 Vol.115 - -

Chemical Name	N,N-Dimethylformamide(Gas)
Bacterial Test	Negative
CHL/IU Test	-