GHS Classification Result (Revision of the past classification result)

Chemical Name:Acrolein
CAS:107-02-8

Result:
ID: H26-B-003 / -
Classifier: Ministry of Health, Labour and Welfare (MHLW), Ministry of the Environment (MOE)
Year Classified: FY2014
Reference Manual: GHS Classification Guidance for the Japanese Government (August 2013)

PHYSICAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Explosives Not applicable - - - - -
2 Flammable gases (including chemically unstable gases) Not applicable - - - - -
3 Aerosols Not applicable - - - - -
4 Oxidizing gases Not applicable - - - - -
5 Gases under pressure Not applicable - - - - -
6 Flammable liquids Category 2 Danger H225: Highly flammable liquid and vapour P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P370+P378: In case of fire: Use ... to extinguish.
P403+P235: Store in a well-ventilated place. Keep cool.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/lighting/.../equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P501: Dispose of contents/container to ...
-
7 Flammable solids Not applicable - - - - -
8 Self-reactive substances and mixtures Type G - - - - -
9 Pyrophoric liquids Not classified - - - - -
10 Pyrophoric solids Not applicable - - - - -
11 Self-heating substances and mixtures Classification not possible - - - - -
12 Substances and mixtures which, in contact with water, emit flammable gases Not applicable - - - - -
13 Oxidizing liquids Not applicable - - - - -
14 Oxidizing solids Not applicable - - - - -
15 Organic peroxides Not applicable - - - - -
16 Corrosive to metals Classification not possible - - - - -

HEALTH HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
1 Acute toxicity (Oral) Category 2 Danger H300: Fatal if swallowed P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/....
P361+P364: Take off immediately all contaminated clothing and wash it before reuse.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P321: Specific treatment (see ... on this label).
P330: Rinse mouth.
P405: Store locked up.
P501: Dispose of contents/container to ...
-
1 Acute toxicity (Dermal) Category 3 Danger H311: Toxic in contact with skin P302+P352: IF ON SKIN: Wash with plenty of water/....
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER/doctor/... / if you feel unwell.
P321: Specific treatment (see ... on this label).
P361: Take off immediately all contaminated clothing.
P364: And wash it before reuse.
P405: Store locked up.
P501: Dispose of contents/container to ...
-
1 Acute toxicity (Inhalation: Gases) Not applicable - - - - -
1 Acute toxicity (Inhalation: Vapours) Category 1 Danger H330: Fatal if inhaled P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P284: [In case of inadequate ventilation] wear respiratory protection.
P310: Immediately call a POISON CENTER/doctor/....
P320: Specific treatment is urgent (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
-
1 Acute toxicity (Inhalation: Dusts and mists) Classification not possible - - - - -
2 Skin corrosion/irritation Category 1 Danger H314: Causes severe skin burns and eye damage P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash ... thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P310: Immediately call a POISON CENTER/doctor/....
P321: Specific treatment (see ... on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to ...
-
3 Serious eye damage/eye irritation Category 1 Danger H318: Causes serious eye damage P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P310: Immediately call a POISON CENTER/doctor/....
-
4 Respiratory sensitization Classification not possible - - - - -
4 Skin sensitization Classification not possible - - - - -
5 Germ cell mutagenicity Classification not possible - - - - -
6 Carcinogenicity Classification not possible - - - - -
7 Reproductive toxicity Not classified - - - - -
8 Specific target organ toxicity - Single exposure Category 1 (respiratory system, central nervous system, liver), Category 3 (narcotic effects) Danger
Warning
H370: Causes damage to organs (respiratory system, central nervous system, liver)
H336: May cause drowsiness or dizziness (narcotic effects)
P308+P311: IF exposed or concerned: Call a POISON CENTER/doctor/....
P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P321: Specific treatment (see ... on this label).
P405: Store locked up.
P501: Dispose of contents/container to ...
P304+P340: IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P403+P233: Store in a well-ventilated place. Keep container tightly closed.
P261: Avoid breathing dust/fume/gas/mist/vapours/spray.
P271: Use only outdoors or in a well-ventilated area.
P312: Call a POISON CENTER/doctor/... / if you feel unwell.
-
9 Specific target organ toxicity - Repeated exposure Category 1 (respiratory system) Danger H372: Cause damage to organs through prolonged or repeated exposure (respiratory system) P260: Do not breathe dust/fume/gas/mist/vapours/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P314: Get medical advice/attention if you feel unwell.
P501: Dispose of contents/container to ...
-
10 Aspiration hazard Classification not possible - - - - -

ENVIRONMENTAL HAZARDS
Hazard class Classification Symbol Signal word Hazard statement Precautionary statement Rationale for the classification
11 Hazardous to the aquatic environment (Acute) - - - - - -
11 Hazardous to the aquatic environment (Long-term) - - - - - -
12 Hazardous to the ozone layer - - - - - -


NOTE:
* Classification was conducted by relevant Japanese Ministries in accordance with GHS Classification Guidance for the Japanese Government, and is intended to provide a reference for preparing GHS labelling and SDS for users.
* This is a provisional English translation of classification results and is subject to revision without notice.
* The responsibility for any resulting GHS labelling and SDS referenced from this site is with users.

Reference:
Reference Manual

Definitions / Abbreviations

Model SDS by MHLW

MHLW Website (in Japanese Only)


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