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General Information
- General Information
  - General Information Data Description
    - CHRIP_ID C004-726-00A CAS RN 121-14-2
      
      Chemical Substance Name 2,4-Dinitrotoluene
      
      Molecular Formula C7H6N2O4
      
      Molecular Weight 182
      
      SMILES O=[N+]([O-])C1=CC([N+]([O-])=O)=CC=C1C
      
      Structure
- Synonym
  - Synonym Data Description
    - Synonym 2,4-Dinitrotoluene
      
      1-Methyl-2,4-dinitrobenzene
      
      2,4-DNT
      
      Benzene, 1-methyl-2,4-dinitro-
- Nikkaji
  - Information of Japan Chemical Substance Dictionary (Nikkaji) Data Description
    - Nikkaji Number
      J2.922J
      Detail to J-GLOBAL

Laws and Regulations in Japan

Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc. (Chemical Substances Control Law ; CSCL)

Japan CSCL: Canceled Priority Assessment Chemical Substances Data Description

Registration Number	61	Date of Cancellation	2014/10/01
MITI Number	3-446	Date of designation as a priority assessment chemical substance	2011/04/01
Chemical Substance Name	Dinitrotoluene
Remarks	-
Remarks of Cancellation	-
Details	to J-CHECK

Japan CSCL: Existing Chemical Substances Data Description Definition of the terms of Section 6 [PDF] Definition of the terms of Section 7 [PDF] Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]

MITI Number	3-446	Category	Section 3
Chemical Substance Name	Dinitrotoluene
Remarks	-
Details	to J-CHECK
Remarks to Existing Chemical Substances of Industrial Safety and Health Act	Chemicals have been notified in accordance with the provisions of Chemical Substances Control Law by June 29, 1979
Details to Existing Chemical Substances of Industrial Safety and Health Act	to MHLW site (in Japanese)

Japan CSCL: Type II Monitoring Chemical Substances (before amendment) Data Description Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]
- Registration Number
  412
  Date of Designation in the Official Gazette 2000/09/22
  
  MITI Number
  3-446
  
  Chemical Substance Name Dinitrotoluene
  
  Remarks -
  
  Details to J-CHECK

Japan CSCL: Type III Monitoring Chemical Substances (before amendment) Data Description Import Clearance Procedures[PDF] Notification of the Manufacturing Amount, etc[PDF]
- Registration Number
  25
  Date of Designation in the Official Gazette 2006/07/18
  
  MITI Number
  3-446
  
  Chemical Substance Name Dinitrotoluene
  
  Remarks -
  
  Details to J-CHECK

Act on Confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management Thereof(PRTR-SDS Law)

Japan: PRTR-SDS Law (until March 2023) Data Description Outline PRTR Law (METI site) Analysis of PRTR data

Classification	I	Cabinet Order Number	1-200
Cabinet Order Name	Dinitrotoluene
Remarks	-
Basis of selection	Hazard Data (in Japanese)
Link	Releases Map (in Japanese) Atmospheric concentration Map (in Japanese)

Japan: PRTR-SDS Law (from April 2023) Data Description Outline PRTR Law (METI site)

JPSN(Japan PRTR-SDS Number)	200	Classification	I	Cabinet Order Number	1-227
Cabinet Order Name	Dinitrotoluene
Remarks	-
Basis of selection	Hazard Data (in Japanese)
Link	- -

Industrial Safety and Health Act (ISHA)

Japan ISHA: Chemical Substances Requiring Labeling and Delivery of Documents, etc. Data Description GHS compatible model label creation method (MH LW site : in Japanese) Risk assessment implementation support tool (MHLW site : in Japanese)
- Cabinet Order Number
  Attached table 9-272 of Cabinet order
  
  Cabinet Order Name 2,4-Dinitrotoluene
  
  Range of Application for Label (weight%) >=1
  
  Range of Application for SDS (weight%) >=0.1

Japan ISHA: Carcinogenic Substances (Ordinance on Industrial Safety and Health) (subject to 30-year storage of work records, etc.) Data Description Lists of Target Substances (MHLW site : in Japanese)

GHS Classification Substance Name	2,4-Dinitrotoluene
Carcinogenicity in GHS classification	Category 1B	Range of Application (weight%)	>=0.1
Implementation	2023/4/1
Details	to the GHS Classification

Japan ISHA: Strong Mutagenic Chemical Substances Data Description Related information (MHLW site : in Japanese)
- Classification Existing Chemical Substances
  
  Name 2,4-Dinitrotoluene
  
  Date of Notification 1993/05/17 Appendix2(2-27)

Poisonous and Deleterious Substances Control Act
- Japan Poisonous and Deleterious Substances Control Act Data Description Link to the Act (MOJ site)
  - Classification Deleterious Substances(Cabinet order) Law or Cabinet Order Number
    Article 2-1-43-2 of Cabinet order
    
    Law or Cabinet Order Name 2,4-Dinitrotoluene and preparations containing it

Air Pollution Control Act
- Japan Air Pollution Control Law Data Description Air & Transportation (MOE site)
  - Classification Substances that may be classified as Hazardous Air Pollutants Cabinet Order Number
    86 of Central Environment Council 9th Report (Appendix 1)
    
    Cabinet Order Name Dinitrotoluene

Fire Service Act

Fire Service Act : Hazardous Materials Data Description

Number of cabinet order etc.	Article 2, Paragraph 7 of the Act, Appended Table 1, Category V (3)
Category; Property	Category V; Self-Reactive Substances
Item	Nitro compounds
Sources	MHLW Website; Sample SDS

Laws and Regulations in Other countries

Recommendations on the transport of dangerous goods
- Dangerous Goods List (UN Number and Hazard class) Data Description
  - UN Number
    1600
    Class or Division 6.1
    
    Name and Description DINITROTOLUENES, MOLTEN
    
    UN packing group II
    
    UN Number
    3454
    Class or Division 6.1
    
    Name and Description DINITROTOLUENES, SOLID
    
    UN packing group II

Association of South-East Asian Nations(ASEAN)
- The ASEAN-Japan Chemical Safety Database (AJCSD).: Laws and Regulations Data Description
  - Detail to AJCSD

European Union (EU)

EC Inventory Data Description
- EC Number
  204-450-0
  
  EC Name 2,4-dinitrotoluene
  
  Description -
  
  Substance Infocard Infocard
  
  ECHA Name -

REACH: Substances of Very High Concern for Authorization (SVHC) Data Description
- EC Number 204-450-0 Status Authorisation List
  
  Substance Name 2,4-dinitrotoluene (2,4-DNT)
  
  Intrinsic property
  Carcinogenic (Article 57a)
  
  Sunset Date
  2015/08/21
  
  Details to ECHA site
  
  EC Number 204-450-0 Status Candidate List
  
  Substance Name 2,4-dinitrotoluene
  
  Reason for inclusion
  Carcinogenic (Article 57a)
  
  Date of inclusion
  2010/01/13
  
  Details to ECHA site

EU: CLP Harmonised Classification Data Description To ECHA site

Index Number	609-007-00-9	EC Number	204-450-0
Chemical Name	2,4-dinitrotoluene [1], dinitrotoluene [2]
Individual substance name	2,4-dinitrotoluene
Classification	Carc. 1B / Muta. 2 / Repr. 2 / [Inh.]Acute Tox. 3 * / [Der.]Acute Tox. 3 * / [Oral]Acute Tox. 3 * / STOT RE 2 * / Aquatic Acute 1 / Aquatic Chronic 1

US: Toxic Substances Control Act (TSCA)
- TSCA Inventory Data Description
  - TSCA Chemical Substance Name Benzene, 1-methyl-2,4-dinitro-
    
    DEF -
    
    UVCB -
    
    FLAG -
    
    ACTIVITY ACTIVE

China
- China: Catalog of Hazardous Chemicals 2015 Data Description
  - Number
    607
    
    Name 2,4-Dinitrotoluene
    
    Other Name -
    
    Remarks -

Korea

Korea: ARECs (K-REACH) / CCA; Hazardous Substance(s), Priority Control Substances Data Description
- Number
  2014-1-695
  
  Category Toxic Substance(s)
  
  Chemical Substance Name Dinitrotoluene
  
  Range of Application (%)
  >=0.1
  
  Number
  105
  
  Category Priority Control Substances
  
  Chemical Substance Name 2,4-Dinitrotoluene

Korea: ARECs (K-REACH); Existing Chemical Substances Data Description

KE Number	KE-23776
Category	Existing Chemical Substances (Domestically distributed commercial purpose before February 2, 1991.)
Chemical Substance Name	2,4-Dinitrotoluene
Remarks	In the case of being hydrated, the resulting hydrate is also applicable.

Korea: ARECs (K-REACH); Others Data Description
- Number 156
  
  Category Phase-in substance(s) subject to registration (by June 30, 2018)
  
  Chemical Substance Name 2,4-Dinitrotoluene
  
  Note
  The registration grace period is until June 30, 2018

Taiwan
- Taiwan: TCCSCA/OSHA; Existing Chemical Substances Data Description
  - English Name 2,4-dinitrotoluene
    
    Chinese Name -

Chemical Hazard and Risk Information

GHS Classification Results

NITE Japan-GHS Data Description
- Edition version_2
  
  Chemical Substance Name 2,4-Dinitrotoluene
  
  Classification Result To the resut webpage To the Excel flie

GHS Classification Results by the Japanese Government Data Description GHS Information

Year of implementation /renewal	2006	ID	33_H18_new
Chemical Substance Name	2,4-Dinitrotoluene
Classification Result	To the resut webpage To the Excel flie

Year of implementation /renewal	2014	ID	- / R-101
Chemical Substance Name	2,4-Dinitrotoluene
Classification Result	To the resut webpage To the Excel flie
Remarks	The reclassification result of only environmental hazard classes. As for physical and health hazard classes, please see the result in FY2006.

Year of implementation /renewal	2020	ID	R02-B-012-MHLW, MOE
Chemical Substance Name	2,4-Dinitrotoluene
Classification Result	To the resut webpage To the Excel flie

MHLW:GHS Aligned Sample Label and SDS
- GHS Aligned Sample Label and SDS Data Description Information on GHS Aligned Sample Label and SDS (Workplace Safety Site)
  - Chemical Substance Name 2,4-Dinitrotoluene
    
    Sample Label to MHLW Website (in Japanese Only)
    
    Sample SDS to MHLW Website (in Japanese Only)

AIST: Relational Information System for Chemical Accidents Database(RISCAD)
- Relational Information System for Chemical Accidents Database(RISCAD) Data Description RISCAD (in Japanese)
  - Material ID 1958
    
    Name 2,4-dinitrotoluene
    
    Material Information to RISCAD

Hazard and Risk Assessment Reports etc. in Japan

Chemical Substances Hazard Assessment Report / Initial Risk Assessment Report Data Description Guidance for Initial Risk Assessment ver.1 (in Japanese) Guidance for Initial Risk Assessment ver.2 (in Japanese)

Report Number	No.51
Assessed Chemical Substance Name	Dinitrotoluene
Details	Hazard Assessment Report (in Japanese)	Date of publication/ renewal	2004/09
	Details Initial Risk Assessment Report (in Japanese)	Date of publication/ renewal	2005/05
	Details Summary of Initial Risk Assessment Report	Date of publication/ renewal	2010/05

ISHA: Risk Assessment Report Data Description to MHLW site (in Japanese)
- Name 2,4-Dinitrotoluene
  
  Initial Risk Assessment Report text/cover (in Japanese)
  
  Full Risk Assessment Report text/cover (in Japanese)

Hazard Data Sheet for Chemical Substances Data Description
- Book Number
  98-15(1)
  Date of publication/ renewal 1999/08
  
  Assessed Chemical Substance Name 2,4-Dinitrotoluene
  
  Details Hazard Data Sheet (in Japanese)

Hazard and Risk Assessment Reports etc. in Other Countries
- OECD: High Production Volume (HPV) Chemicals Data Description
  - Chemical Name 2,4-Dinitrotoluene
    
    Details to OECD Existing Chemicals Database
- International Chemical Safety Cards (ICSC) Data Description
  - ICSC Number
    727
    
    ICSC Title 2,4-Dinitrotoluene
    
    Details to ILO site
- US Agency for Toxic Substances and Disease Registry (ATSDR): Toxicological Profiles Data Description
  - Profile Title Dinitrotoluenes
    
    Details to ATSDR site
    
    Date of Issue February 2016
- US EPA: Integrated Risk Information System (IRIS) Data Description
  - Chemical Substance Name 2,4-Dinitrotoluene
    
    Details to EPA site Last Revision 1992/06/01
- EU: Risk Assessment Reports (RAR) Data Description
  - EC Number
    204-450-0
    Date 2008/11/28
    
    Report Title 2,4-DINITROTOLUENE
    
    Details to ECHA site
- Advisory Committee on Existing Chemicals (BUA) Reports by the German Chemical Society Data Description
  - BUA Number
    12, 114
    
    Substance Name 2,4-Dinitrotoluene
    
    Related information to BUA site

Japan Society for Occupational Health (JSOH) Recommendation of Occupational Exposure Limits
- JSOH: Occupational Carcinogens Data Description
  - Substance Name 2,4-(or 2,6-) Dinitrotoluene
    
    Carcinogenicity classification 2B
    
    Details -
    
    Year of proposal 1998
    
    Remarks -

Carcinogenicity Assessment
- IARC: Carcinogenicity Assessment Data Description to IARC site
  - Volume 65 Volume publication year 1996
    
    Agent Name 2,4-Dinitrotoluene
    
    Group 2B
    
    Details Vol.65 - - - -
- US EPA: Carcinogenicity Assessment Data Description to EPA site
  - Chemical Substance Name 2,4-/2,6-Dinitrotoluene mixture
    
    Guideline: Category 1986 : B2
    
    Exporsure Route Oral route
    
    Details to Substance Profile
- European Union (EU): Carcinogenicity Assessment Data Description to ECHA site
  - Substance Name 2,4-dinitrotoluene
    
    Category Code 1B

Test Data and Reports
- Test Data and Reports
  - ISHA: Mutagenicity Test Results for Chemical Substances Data Description to MHLW site (in Japanese)
    - Chemical Name 2,4-Dinitrotoluene
      
      Bacterial Test -
      
      CHL/IU Test Positive
  - US National Toxicology Program (NTP) : Long-Term Study Reports & Abstracts Data Description
    - Report Number
      TR-54
      
      Report Title Bioassay of 2,4-Dinitrotoluene for Possible Carcinogenicity (CASRN 121-14-2)
      
      Abstract to NTP site Full Text to NTP site

CHRIP_ID	C004-726-00A	CAS RN	121-14-2
Chemical Substance Name	2,4-Dinitrotoluene
Molecular Formula	C7H6N2O4
Molecular Weight	182
SMILES	O=[N+]([O-])C1=CC([N+]([O-])=O)=CC=C1C
Structure

Synonym	2,4-Dinitrotoluene
	1-Methyl-2,4-dinitrobenzene
	2,4-DNT
	Benzene, 1-methyl-2,4-dinitro-

Registration Number	412	Date of Designation in the Official Gazette	2000/09/22
MITI Number	3-446
Chemical Substance Name	Dinitrotoluene
Remarks	-
Details	to J-CHECK

Registration Number	25	Date of Designation in the Official Gazette	2006/07/18
MITI Number	3-446
Chemical Substance Name	Dinitrotoluene
Remarks	-
Details	to J-CHECK

Cabinet Order Number	Attached table 9-272 of Cabinet order
Cabinet Order Name	2,4-Dinitrotoluene
Range of Application for Label (weight%)	>=1
Range of Application for SDS (weight%)	>=0.1

Classification	Existing Chemical Substances
Name	2,4-Dinitrotoluene
Date of Notification	1993/05/17 Appendix2(2-27)

Classification	Deleterious Substances(Cabinet order)	Law or Cabinet Order Number	Article 2-1-43-2 of Cabinet order
Law or Cabinet Order Name	2,4-Dinitrotoluene and preparations containing it

Classification	Substances that may be classified as Hazardous Air Pollutants	Cabinet Order Number	86 of Central Environment Council 9th Report (Appendix 1)
Cabinet Order Name	Dinitrotoluene

UN Number	1600	Class or Division	6.1
Name and Description	DINITROTOLUENES, MOLTEN
UN packing group	II

UN Number	3454	Class or Division	6.1
Name and Description	DINITROTOLUENES, SOLID
UN packing group	II

EC Number	204-450-0	Status	Authorisation List
Substance Name	2,4-dinitrotoluene (2,4-DNT)
Intrinsic property	Carcinogenic (Article 57a)
Sunset Date	2015/08/21
Details	to ECHA site

TSCA Chemical Substance Name	Benzene, 1-methyl-2,4-dinitro-
DEF	-
UVCB	-
FLAG	-
ACTIVITY	ACTIVE

Number	156
Category	Phase-in substance(s) subject to registration (by June 30, 2018)
Chemical Substance Name	2,4-Dinitrotoluene
Note	The registration grace period is until June 30, 2018

Material ID	1958
Name	2,4-dinitrotoluene
Material Information	to RISCAD

EC Number	204-450-0
EC Name	2,4-dinitrotoluene
Description	-
Substance Infocard	Infocard
ECHA Name	-

Number	2014-1-695
Category	Toxic Substance(s)
Chemical Substance Name	Dinitrotoluene
Range of Application (%)	>=0.1

Number	105
Category	Priority Control Substances
Chemical Substance Name	2,4-Dinitrotoluene

Edition	version_2
Chemical Substance Name	2,4-Dinitrotoluene
Classification Result	To the resut webpage To the Excel flie

Chemical Substance Name	2,4-Dinitrotoluene
Sample Label	to MHLW Website (in Japanese Only)
Sample SDS	to MHLW Website (in Japanese Only)

Name	2,4-Dinitrotoluene
Initial Risk Assessment Report	text/cover (in Japanese)
Full Risk Assessment Report	text/cover (in Japanese)

Book Number	98-15(1)	Date of publication/ renewal	1999/08
Assessed Chemical Substance Name	2,4-Dinitrotoluene
Details	Hazard Data Sheet (in Japanese)

ICSC Number	727
ICSC Title	2,4-Dinitrotoluene
Details	to ILO site

Profile Title	Dinitrotoluenes
Details	to ATSDR site
Date of Issue	February 2016

EC Number	204-450-0	Date	2008/11/28
Report Title	2,4-DINITROTOLUENE
Details	to ECHA site

BUA Number	12, 114
Substance Name	2,4-Dinitrotoluene
Related information	to BUA site

Substance Name	2,4-(or 2,6-) Dinitrotoluene
Carcinogenicity classification	2B
Details	-
Year of proposal	1998
Remarks	-

Volume	65	Volume publication year	1996
Agent Name	2,4-Dinitrotoluene
Group	2B
Details	Vol.65 - - - -

Chemical Substance Name	2,4-/2,6-Dinitrotoluene mixture
Guideline: Category	1986 : B2
Exporsure Route	Oral route
Details	to Substance Profile

Chemical Name	2,4-Dinitrotoluene
Bacterial Test	-
CHL/IU Test	Positive

Report Number	TR-54
Report Title	Bioassay of 2,4-Dinitrotoluene for Possible Carcinogenicity (CASRN 121-14-2)
Abstract	to NTP site	Full Text	to NTP site